3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-1,2-di-O-6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoylglycerol

Base Information

Chemical Name:3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-1,2-di-O-6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoylglycerol
CAS No.:1432064-22-6
Molecular Formula:C₇₈H₉₄O₁₀S
Molecular Weight:1223.66
Hs Code.:

Synonyms:

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Chemical Property of 3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-1,2-di-O-6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoylglycerol

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Technology Process of 3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-1,2-di-O-6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoylglycerol

There total 5 articles about 3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-1,2-di-O-6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoylglycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 96861-28-8
6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoic acid

: 265312-95-6
3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-glycerol

: 1432064-22-6
3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-1,2-di-O-6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoylglycerol

Guidance literature:: With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃; for 20h;
DOI:10.1002/chem.201203296

Reference yield:

: 265312-93-4
1-O-allyl-2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranoside

: 1432064-22-6
3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-1,2-di-O-6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoylglycerol

Guidance literature:: Multi-step reaction with 2 steps

1: AD-mix-α / tert-butyl alcohol; water / 22 h / 20 °C

2: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 20 h / 20 °C

With dmap; AD-mix-α; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; water; tert-butyl alcohol;
DOI:10.1002/chem.201203296

Reference yield:

: 17814-85-6
(4-carboxybutyl)triphenylphosphonium bromide

: 1432064-22-6
3-O-(2,3,4-tri-O-benzyl-6-deoxy-6-thioacetyl-α-D-glucopyranosyl)-1,2-di-O-6-(4'-pentyl-[1,1'-biphenyl]-4-yl)hexanoylglycerol

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran

1.2: 24 h / 20 °C

2.1: palladium 10% on activated carbon; hydrogen / ethanol / 20 °C

3.1: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 20 h / 20 °C

With dmap; palladium 10% on activated carbon; hydrogen; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; lithium hexamethyldisilazane; In tetrahydrofuran; ethanol; dichloromethane; 1.1: |Wittig Olefination;
DOI:10.1002/chem.201203296