Technology Process of Ru(4,4'-dicarboxyl-2,2'-bipyridine)[4,4'-bis(4-styrylaminocarbonyl)-2,2'-bipyridine](NCS)2
There total 3 articles about Ru(4,4'-dicarboxyl-2,2'-bipyridine)[4,4'-bis(4-styrylaminocarbonyl)-2,2'-bipyridine](NCS)2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: sulfuric acid; potassium dichromate
2.1: N,N-dimethyl-formamide / 4 h / 80 °C / Darkness; Inert atmosphere
2.2: 4 h / 160 °C / Inert atmosphere
2.3: 5 h / 130 °C / Inert atmosphere
With
potassium dichromate; sulfuric acid;
In
N,N-dimethyl-formamide;
DOI:10.1039/c3ta01567j
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: thionyl chloride / Reflux; Inert atmosphere
2.1: triethylamine / tetrahydrofuran
3.1: N,N-dimethyl-formamide / 4 h / 80 °C / Darkness; Inert atmosphere
3.2: 4 h / 160 °C / Inert atmosphere
3.3: 5 h / 130 °C / Inert atmosphere
With
thionyl chloride; triethylamine;
In
tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1039/c3ta01567j
- Guidance literature:
-
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; N4,N4′-bis(4-vinylphenyl)-2,2′-bipyridine-4,4′-dicarboxamide;
In
N,N-dimethyl-formamide;
at 80 ℃;
for 4h;
Darkness;
Inert atmosphere;
2,2'-Bipyridine-4,4'-dicarboxylic acid;
In
N,N-dimethyl-formamide;
at 160 ℃;
for 4h;
Inert atmosphere;
ammonium thiocyanate;
In
N,N-dimethyl-formamide;
at 130 ℃;
for 5h;
Inert atmosphere;
DOI:10.1039/c3ta01567j
