(C₅H₄)2Si(CH₃)2Fe₂(CO)3CC₆H₄CF₃SC₆H₄CH₃

Base Information

• Chemical Name: (C₅H₄)2Si(CH₃)2Fe₂(CO)3CC₆H₄CF₃SC₆H₄CH₃
• CAS No.: 372110-83-3
• Molecular Formula: C₃₀H₂₅F₃Fe₂O₃SSi
• Molecular Weight: 662.367
• Mol file: 372110-83-3.mol

Synonyms:

Chemical Property of (C₅H₄)2Si(CH₃)2Fe₂(CO)3CC₆H₄CF₃SC₆H₄CH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₅H₄)2Si(CH₃)2Fe₂(CO)3CC₆H₄CF₃SC₆H₄CH₃

There total 1 articles about (C₅H₄)2Si(CH₃)2Fe₂(CO)3CC₆H₄CF₃SC₆H₄CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

[Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4 (372110-72-0) + sodium p-thiocresolate (10486-08-5) → (C5H4)2Si(CH3)2Fe2(CO)3CC6H4CF3SC6H4CH3 (372110-83-3)

Guidance literature:

In tetrahydrofuran; (N2); addn. of sulfur compd. to a soln. of iron compd. in THF at -80°C, stirring at -80 to -60°C for 1 h, stirring at -60 to -20°C for 3 h; evapn. at -30°C. column chromy (Al2O3, -25°C, petroleum ether/CH2Cl2 10:1), evapn., recrystn. (petroleum ether/CH2Cl2 15:1, -80°C); elem. anal.;

DOI:10.1021/om010322r

upstream raw materials:

[Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4

sodium p-thiocresolate