[Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4

Base Information

• Chemical Name: [Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4
• CAS No.: 372110-72-0
• Molecular Formula: BBr₄*C₂₃H₁₈F₃Fe₂O₃Si
• Molecular Weight: 869.596
• Mol file: 372110-72-0.mol

Synonyms:

Chemical Property of [Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4

There total 1 articles about [Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

[Fe2(μ-CO)(μ-C(OEt)C6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)] (331637-92-4) + boron tribromide (10294-33-4) → [Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4 (372110-72-0)

Guidance literature:

In diethyl ether; (N2); addn. of a soln. of iron complex in ether to boron compd. at -65°C, stirring for 10 min; filtration, washing with ether at -65°C, drying in vac. at -50°C;

DOI:10.1021/om010322r

Reference yield: 83.0%

Na[W(CO)5CN] + dichloromethane (75-09-2) + [Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4 (372110-72-0) → [Fe2(μ-CO)(μ-C(C6H4CF3-p)NCW(CO)5)(CO)2((η5-C5H4)2Si(CH3)2)]

Guidance literature:

In tetrahydrofuran; (N2); addn. of W complex to a soln. of iron complex in THF at -100°C, stirring at -100 to -80°C for 1 h, stirring at -80 to -50°C for 4 h; evapn. at -45°C, column chromy. (Al2O3, -25°C, petroleum ether/CH2Cl2 10:1), evapn., recrystn. (petroleum ether/CH2Cl2, 15:1, -80°C); elem. anal.;

DOI:10.1016/S0022-328X(02)01661-3

Reference yield: 78.0%

[Fe2(μ-CO)(μ-CC6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]BBr4 (372110-72-0) + sodium p-thiocresolate (10486-08-5) → (C5H4)2Si(CH3)2Fe2(CO)3CC6H4CF3SC6H4CH3 (372110-83-3)

Guidance literature:

In tetrahydrofuran; (N2); addn. of sulfur compd. to a soln. of iron compd. in THF at -80°C, stirring at -80 to -60°C for 1 h, stirring at -60 to -20°C for 3 h; evapn. at -30°C. column chromy (Al2O3, -25°C, petroleum ether/CH2Cl2 10:1), evapn., recrystn. (petroleum ether/CH2Cl2 15:1, -80°C); elem. anal.;

DOI:10.1021/om010322r

upstream raw materials:

[Fe2(μ-CO)(μ-C(OEt)C6H4CF3-p)(CO)2((η5-C5H4)2Si(CH3)2)]

boron tribromide

Downstream raw materials:

(C₅H₄)2Si(CH₃)2Fe₂(CO)3CC₆H₄CF₃SC₆H₅

(C₅H₄)2Si(CH₃)2Fe₂(CO)3CC₆H₄CF₃SC₆H₄CH₃

(C₅H₄)2Si(CH₃)2Fe₂(CO)3CC₆H₄CF₃SCH₃