mer-dichloro(triphenylphosphine){phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}ruthenium(II)

Base Information

• Chemical Name: mer-dichloro(triphenylphosphine){phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}ruthenium(II)
• CAS No.: 121962-48-9
• Molecular Formula: C₅₂H₅₂Cl₂P₄Ru
• Molecular Weight: 972.856
• Mol file: 121962-48-9.mol

Synonyms:

Chemical Property of mer-dichloro(triphenylphosphine){phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mer-dichloro(triphenylphosphine){phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}ruthenium(II)

There total 1 articles about mer-dichloro(triphenylphosphine){phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + bromo{phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}nickel(II) bromide-dichloromethane (121935-47-5) → mer-dichloro(triphenylphosphine){phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}ruthenium(II) (121962-48-9)

Guidance literature:

In dichloromethane; Refluxing of phosphine ligand with Ru-complex under N2 for 4 h.; Evapn., addn. of hexane, standing in refrigerator (1 h), filtn., evapn. of filtrate to dryness, dissolving of residue in diethyl ether, filtn., 24 h at room temp., drying in vac. over night, elem. anal.;

DOI:10.1021/ic00317a012

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

bromo{phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}nickel(II) bromide-dichloromethane