{(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}⁽¹⁺⁾*PF₆^(1-)={(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}(PF₆)

Base Information

• Chemical Name: {(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}⁽¹⁺⁾*PF₆^(1-)={(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}(PF₆)
• CAS No.: 139565-70-1
• Molecular Formula: C₂₉H₃₅P₂Ru*F₆P
• Molecular Weight: 691.579
• Mol file: 139565-70-1.mol

Synonyms:

Chemical Property of {(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}⁽¹⁺⁾*PF₆^(1-)={(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}(PF₆)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}⁽¹⁺⁾*PF₆^(1-)={(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}(PF₆)

There total 1 articles about {(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}⁽¹⁺⁾*PF₆^(1-)={(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2}(PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate + diallyl-phenyl-phosphane (29949-75-5) → {(C5H5)Ru((C6H5)P(CH2CHCH2)2)2}(1+)*PF6(1-)={(C5H5)Ru((C6H5)P(CH2CHCH2)2)2}(PF6) (139565-70-1)

Guidance literature:

In acetonitrile; addn. of 2 equiv of DAPP to soln. of (CpRu(CH3CN)3)PF6 in acetonitrile (under N2), stirred (overnight); evapn., washed with ether, crystn. from CH2Cl2/ Et2O, recrystn. from CH2Cl2/ Et2O; elem. anal.; mixt. of 2 isomers in ratio 19:1 (NMR);;

DOI:10.1021/om00040a036

Reference yield:

{(C5H5)Ru((C6H5)P(CH2CHCH2)2)2}(1+)*PF6(1-)={(C5H5)Ru((C6H5)P(CH2CHCH2)2)2}(PF6) (139565-70-1) → {(C5H5)Ru((C6H5)P(CH2CHCH2)2)2(CH3CN)}(1+)*PF6(1-)={(C5H5)Ru((C6H5)P(CH2CHCH2)2)2(CH3CN)}(PF6) (139565-68-7)

Guidance literature:

With CH₃CN; In chloroform-d1; addn. of CH3CN to soln. of the Ru complex in CDCl3; not isolated; 31P-NMR;

DOI:10.1021/om00040a036

Reference yield:

{(C5H5)Ru((C6H5)P(CH2CHCH2)2)2}(1+)*PF6(1-)={(C5H5)Ru((C6H5)P(CH2CHCH2)2)2}(PF6) (139565-70-1) → {(C5H5)Ru((C6H5)P(CH2CHCH2)2)2(CO)}(1+)*PF6(1-)={(C5H5)Ru((C6H5)P(CH2CHCH2)2)2(CO)}(PF6)

Guidance literature:

With CO; In not given; quantitative conversion;;

DOI:10.1021/om00040a036

upstream raw materials:

diallyl-phenyl-phosphane

Downstream raw materials:

{(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2(CH₃CN)}⁽¹⁺⁾*PF₆^(1-)={(C₅H₅)Ru((C₆H₅)P(CH₂CHCH₂)2)2(CH₃CN)}(PF₆)