(CH₃)2C₆H₃CH₂NH₂CH₂C₆H₄OCH₂C₆H₄CHCHRuCl(CO)(P(C₆H₅)3)2⁽¹⁺⁾*C₄H₁₀O*C₂₄H₃₂O₈*PF₆^(1-)=C₂₄H₃₂O₈[C₆₂H₅₇ClNO₂P₂Ru]PF₆*C₄H₁₀O

Base Information

• Chemical Name: (CH₃)2C₆H₃CH₂NH₂CH₂C₆H₄OCH₂C₆H₄CHCHRuCl(CO)(P(C₆H₅)3)2⁽¹⁺⁾*C₄H₁₀O*C₂₄H₃₂O₈*PF₆^(1-)=C₂₄H₃₂O₈[C₆₂H₅₇ClNO₂P₂Ru]PF₆*C₄H₁₀O
• CAS No.: 882532-66-3
• Molecular Formula: C₄H₁₀O*C₂₄H₃₂O₈*C₆₂H₅₇ClNO₂P₂Ru*F₆P
• Molecular Weight: 1714.21
• Mol file: 882532-66-3.mol

Synonyms:

Chemical Property of (CH₃)2C₆H₃CH₂NH₂CH₂C₆H₄OCH₂C₆H₄CHCHRuCl(CO)(P(C₆H₅)3)2⁽¹⁺⁾*C₄H₁₀O*C₂₄H₃₂O₈*PF₆^(1-)=C₂₄H₃₂O₈[C₆₂H₅₇ClNO₂P₂Ru]PF₆*C₄H₁₀O

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (CH₃)2C₆H₃CH₂NH₂CH₂C₆H₄OCH₂C₆H₄CHCHRuCl(CO)(P(C₆H₅)3)2⁽¹⁺⁾*C₄H₁₀O*C₂₄H₃₂O₈*PF₆^(1-)=C₂₄H₃₂O₈[C₆₂H₅₇ClNO₂P₂Ru]PF₆*C₄H₁₀O

There total 1 articles about (CH₃)2C₆H₃CH₂NH₂CH₂C₆H₄OCH₂C₆H₄CHCHRuCl(CO)(P(C₆H₅)3)2⁽¹⁺⁾*C₄H₁₀O*C₂₄H₃₂O₈*PF₆^(1-)=C₂₄H₃₂O₈[C₆₂H₅₇ClNO₂P₂Ru]PF₆*C₄H₁₀O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + dibenzo-24-crown ether (14174-09-5) + diethyl ether (60-29-7,927820-24-4) + (CH3)2C6H3CH2NH2CH2C6H4OCH2C6H4CCH(1+)*PF6(1-)=[(CH3)2C6H3CH2NH2CH2C6H4OCH2C6H4CCH]PF6 (855124-80-0) → (CH3)2C6H3CH2NH2CH2C6H4OCH2C6H4CHCHRuCl(CO)(P(C6H5)3)2(1+)*C4H10O*C24H32O8*PF6(1-)=C24H32O8[C62H57ClNO2P2Ru]PF6*C4H10O (882532-66-3)

Guidance literature:

In chloroform; 1.2 equiv. of the crown-ether was added to a CHCl3 suspn. of the PF6-compd. at ambient temp., 1.0 equiv. of Ru-compd. was added in 30 min, Et2O was added;

DOI:10.1246/cl.2006.212

Reference yield: 75.0%

(CH3)2C6H3CH2NH2CH2C6H4OCH2C6H4CHCHRuCl(CO)(P(C6H5)3)2(1+)*C4H10O*C24H32O8*PF6(1-)=C24H32O8[C62H57ClNO2P2Ru]PF6*C4H10O (882532-66-3) + 1-phenylpropadiene (2327-99-3) → (dibenzo-24-crown-8)((CH3)2C6H3CH2NH2CH2C6H4OCH2C6H4CHCHRu(PhCHCHCH2)PF6)

Guidance literature:

ambient temp., 2 h; preparative HPLC (CHCl3), elem. anal.;

DOI:10.1246/cl.2006.212

Reference yield: 61.0%

(CH3)2C6H3CH2NH2CH2C6H4OCH2C6H4CHCHRuCl(CO)(P(C6H5)3)2(1+)*C4H10O*C24H32O8*PF6(1-)=C24H32O8[C62H57ClNO2P2Ru]PF6*C4H10O (882532-66-3) + cyclohexylallene (5664-17-5) → (dibenzo-24-crown-8)((CH3)2C6H3CH2NH2CH2C6H4OCH2C6H4CHCHRu(C6H11CHCHCH2)PF6)

Guidance literature:

DOI:10.1246/cl.2006.212

upstream raw materials:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

dibenzo-24-crown ether

diethyl ether

(CH₃)2C₆H₃CH₂NH₂CH₂C₆H₄OCH₂C₆H₄CCH⁽¹⁺⁾*PF₆^(1-)=[(CH₃)2C₆H₃CH₂NH₂CH₂C₆H₄OCH₂C₆H₄CCH]PF₆