bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dichlorozirconium

Base Information

Chemical Name:bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dichlorozirconium
CAS No.:835628-61-0
Molecular Formula:C₃₄H₅₂Cl₂P₂Zr
Molecular Weight:684.864
Hs Code.:

Synonyms:

Suppliers and Price of bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dichlorozirconium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dichlorozirconium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dichlorozirconium

There total 1 articles about bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dichlorozirconium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: lithium (dicyclohexylphosphino)cyclopentadienide

: 10026-11-6
zirconium(IV) chloride

: 835628-61-0
bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dichlorozirconium

Guidance literature:: In tetrahydrofuran; toluene; toluene, containing ca.0.4% of THF; slow evapd. of heptane-soln.; elem. anal.;
DOI:10.1021/om049346z

Reference yield: 82.0%

: 835628-61-0
bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dichlorozirconium

: 917-54-4
methyllithium

: 827037-58-1
bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dimethylzirconium

Guidance literature:: In diethyl ether; toluene; byproducts: LiCl; Ar atm.; 2 equiv of CH3Li in diethyl ether was slowly added to a stirredsoln. of complex in toluene at -78°C, over 30 min the temp. was raised to 0°C, stirred for 1 h at 0°C; filtered, the solvent was removed in vac., pentane was added, filtered, washed with pentane, dried in vac.; elem. anal.;
DOI:10.1021/om049346z