bis[1-trimethylsilyl-indenyl]zirconium dichloride

Base Information

• Chemical Name: bis[1-trimethylsilyl-indenyl]zirconium dichloride
• CAS No.: 329703-78-8
• Molecular Formula: C₂₄H₃₀Cl₂Si₂Zr
• Molecular Weight: 536.803
• Mol file: 329703-78-8.mol

Synonyms:

Chemical Property of bis[1-trimethylsilyl-indenyl]zirconium dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis[1-trimethylsilyl-indenyl]zirconium dichloride

There total 1 articles about bis[1-trimethylsilyl-indenyl]zirconium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

3-Trimethylsilylinden (18053-75-3) + zirconium(IV) chloride (10026-11-6) → bis[1-trimethylsilyl-indenyl]zirconium dichloride (329703-78-8,244765-86-4,412009-70-2)

Guidance literature:

With n-BuLi; In tetrahydrofuran; toluene; (Ar); Standard Schlenk technique; n-BuLi added to soln. of ligand in THFat -78°C; warmed to room temp.; stirred for 4 h; solvent removed (vac.); toluene added; ZrCl4/toluene added dropwise at -78°C; wa rmed to room. temp.; stirred for 18 h; NMR monitoring; solvent removed in vac.; CH2Cl2 added; filtered through Celite pad under inert-air atm; pad washed (CH2Cl2); filtrate crystd. at-18°C; elem. anal.;

DOI:10.1016/S0022-328X(00)00570-2

upstream raw materials:

3-Trimethylsilylinden

zirconium(IV) chloride