(η4-C5H5Bu)Fe(CO)2(PPh2Py)

Base Information

• Chemical Name: (η4-C5H5Bu)Fe(CO)2(PPh2Py)
• CAS No.: 371783-18-5
• Molecular Formula: C₂₈H₂₈FeNO₂P
• Molecular Weight: 497.357
• Mol file: 371783-18-5.mol

Synonyms:

Chemical Property of (η4-C5H5Bu)Fe(CO)2(PPh2Py)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η4-C5H5Bu)Fe(CO)2(PPh2Py)

There total 1 articles about (η4-C5H5Bu)Fe(CO)2(PPh2Py) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + n-butyllithium (109-72-8,29786-93-4) + 2-(diphenylphosphino)pyridine (37943-90-1) → (η4-C5H5Bu)Fe(CO)2(PPh2Py) (371783-18-5)

Guidance literature:

In not given; byproducts: LiI; (N2); treatment of iron compd. with phosphine deriv. and butyllithium at-78°C with warming to room temp.; Liu L.-K., Luh L.-S., Organome tallics 13 (1994) 2816, L.-S. Luh, L.-K. Liu, Bull. Inst. Chem., Acad. Sin. 41 (1994) 39;

DOI:10.1016/j.ica.2008.04.040

Reference yield: 81.0%

tris(propionitrile)tricarbonylmolybdenum(0) (103933-26-2) + (η4-C5H5Bu)Fe(CO)2(PPh2Py) (371783-18-5) → (η5-C5H4Bu)Fe(CO)(μ-P:N-PPh2Py)(μ-H)Mo(CO)4

Guidance literature:

In tetrahydrofuran; byproducts: CH3CH2CN; (N2); addn. of dry THF to mixt. of iron compd. and molybdenum, warming to dissolve compds., stiring for 2 h at room temp.; filtration through celite, washing with dry ether, evapn., chromy. (Al2O3, ethyl acetate/n-hexane (1:8 to 1:5)), evapn., elem. anal.;

DOI:10.1016/j.ica.2008.04.040

Reference yield: 76.0%

tris(propionitrile)tungsten tricarbonyl (83732-33-6,84580-21-2) + (η4-C5H5Bu)Fe(CO)2(PPh2Py) (371783-18-5) → (η5-C5H4Bu)Fe(CO)(μ-P:N-PPh2Py)(μ-H)W(CO)4

Guidance literature:

In tetrahydrofuran; byproducts: CH3CH2CN; (N2); addn. of dry THF to mixt. of iron compd. and tungsten, warming to dissolve compds., stiring for 2 h at room temp.; filtration through celite, washing with dry ether, evapn., chromy. (silica gel, ethyl acetate/n-hexane), evapn., elem. anal.;

DOI:10.1016/j.ica.2008.04.040

upstream raw materials:

dicarbonylcyclopentadienyliodoiron(II)

n-butyllithium

2-(diphenylphosphino)pyridine

Downstream raw materials:

(C₄H₉C₅H₄)Fe(CO)2P(C₆H₅)2C₅H₄N⁽¹⁺⁾*BF₄^(1-)=C₄H₉C₅H₄Fe(CO)2P(C₆H₅)2C₅H₄NBF₄