(μ-2-naphthyl)(AuPPh3)2ClO4

Base Information

• Chemical Name: (μ-2-naphthyl)(AuPPh3)2ClO4
• CAS No.: 1034474-09-3
• Molecular Formula: C₄₆H₃₇Au₂P₂*ClO₄
• Molecular Weight: 1145.13
• Mol file: 1034474-09-3.mol

Synonyms:

Chemical Property of (μ-2-naphthyl)(AuPPh3)2ClO4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (μ-2-naphthyl)(AuPPh3)2ClO4

There total 2 articles about (μ-2-naphthyl)(AuPPh3)2ClO4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

perchloric acid (7601-90-3) + (2-naphthyl)(triphenylphosphanyl)gold (67430-86-8) → (μ-2-naphthyl)(AuPPh3)2ClO4 (1034474-09-3)

Guidance literature:

In diethyl ether; HClO4 added to ether soln. of Au-complex at -50°C, stirred for 10min; filtered, washed with cold ether, recrystd. from THF; elem. anal.;

DOI:10.1039/b714609d

Reference yield:

(triphenylphosphine)gold(I) chloride (14243-64-2) + 2-bromonaphthalene (580-13-2) → (μ-2-naphthyl)(AuPPh3)2ClO4 (1034474-09-3)

Guidance literature:

Multi-step reaction with 2 steps

1: Li(CH₂)3CH₃ / hexane; tetrahydrofuran

2: diethyl ether

With Li(CH₂)3CH₃; In tetrahydrofuran; diethyl ether; hexane;

DOI:10.1039/b714609d

upstream raw materials:

perchloric acid

(2-naphthyl)(triphenylphosphanyl)gold

(triphenylphosphine)gold(I) chloride

2-bromonaphthalene