67430-86-8Relevant academic research and scientific papers
Mono- and di-gold(I) naphthalenes and pyrenes: Syntheses, crystal structures, and photophysics
Gao, Lei,Peay, Miya A.,Partyka, David V.,Updegraff III, James B.,Teets, Thomas S.,Esswein, Arthur J.,Zeller, Matthias,Hunter, Allen D.,Gray, Thomas G.
, p. 5669 - 5681 (2010/01/06)
(Phosphine)- and (N-heterocyclic carbene)gold(I) derivatives of naphthalene and pyrene are reported, containing one or two gold atoms per hydrocarbon. The new complexes are prepared by arylation of gold(I) substrates by arylboronic acids or aryl pinacolbo
Photoluminescent properties and molecular structures of [NaphAu(PPh 3)] and [μ-Naph {Au(PPh3)}2] ClO4 (Naph = 2-naphthyl)
Osawa, Masahisa,Hoshino, Mikio,Hashizume, Daisuke
, p. 2248 - 2252 (2008/09/19)
The complexes [NaphAu(PPh3)], 1 and [μ-Naph{Au(PPh 3)}2]ClO4, 2 having the Au-C (aromatic) bond have been synthesized and characterized. The unique structure of 2 with two gold atoms bridged by a naphthyl group has been determined by X-ray crystallography. The intramolecular Au-Au separation in 2 is 2.7731(4) A. Upon excitation at 266 nm, both complexes display intraligand phosphorescence at room temperature in solution and in solid state. This journal is The Royal Society of Chemistry.
