Iodonium, 1-decynylphenyl-, tetrafluoroborate(1-)

Base Information

• Chemical Name: Iodonium, 1-decynylphenyl-, tetrafluoroborate(1-)
• CAS No.: 102987-32-6
• Molecular Formula: C16H22I.BF4
• Molecular Weight: 428.06
• DSSTox Substance ID: DTXSID10452834
• Mol file: 102987-32-6.mol

Synonyms:Iodonium, 1-decynylphenyl-, tetrafluoroborate(1-);102987-32-6;DTXSID10452834

Chemical Property of Iodonium, 1-decynylphenyl-, tetrafluoroborate(1-)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 8
• Exact Mass: 428.07954
• Heavy Atom Count: 22
• Complexity: 246

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [B-](F)(F)(F)F.CCCCCCCCC#C[I+]C1=CC=CC=C1

Technology Process of Iodonium, 1-decynylphenyl-, tetrafluoroborate(1-)

There total 1 articles about Iodonium, 1-decynylphenyl-, tetrafluoroborate(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

iodosylbenzene (536-80-1) + 1-decynyltrimethylsilane (54559-17-0) → 1-decenyl(phenyl)(tetrafluoroborato)-λ3-iodane (102987-32-6)

Guidance literature:

With sodium tetrafluoroborate; boron trifluoride diethyl etherate; In dichloromethane; for 2.5h; Ambient temperature;

DOI:10.1016/S0040-4039(00)88941-8

Reference yield: 100.0%

1-decenyl(phenyl)(tetrafluoroborato)-λ3-iodane (102987-32-6) + Benzenesulfinic acid (618-41-7) → (Z)-[β-(phenylsulfonyl)vinyl]iodonium tetrafluoroborate

Guidance literature:

In methanol; at 0 ℃; for 0.5h;

Reference yield: 100.0%

diphenyl telluride (1202-36-4) + 1-decenyl(phenyl)(tetrafluoroborato)-λ3-iodane (102987-32-6) → 1-decynyl(diphenyl)telluronium tetrafluoroborate

Guidance literature:

In dichloromethane; at 25 ℃; for 3h;

DOI:10.1039/b212512a

upstream raw materials:

iodosylbenzene

1-decynyltrimethylsilane

Downstream raw materials:

nonanoic acid methyl ester

(Z)-2-Chloro-1-decenyl(phenyl)iodonium chloride

(Z)-2-Bromo-1-decenyl(phenyl)iodonium bromide

(Z)-phenyl(2-azido-1-decenyl)iodonium tetrafluoroborate