(((PMe₃Fe)(O₃Si(2,6-iPr₂C₆H₃)N(SiMe₃)))4 ferric siloxane

Base Information

• Chemical Name: (((PMe₃Fe)(O₃Si(2,6-iPr₂C₆H₃)N(SiMe₃)))4 ferric siloxane
• CAS No.: 765277-93-8
• Molecular Formula: C₇₂H₁₄₀Fe₄N₄O₁₂P₄Si₈
• Molecular Weight: 1825.89
• Mol file: 765277-93-8.mol

Synonyms:

Chemical Property of (((PMe₃Fe)(O₃Si(2,6-iPr₂C₆H₃)N(SiMe₃)))4 ferric siloxane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (((PMe₃Fe)(O₃Si(2,6-iPr₂C₆H₃)N(SiMe₃)))4 ferric siloxane

There total 1 articles about (((PMe₃Fe)(O₃Si(2,6-iPr₂C₆H₃)N(SiMe₃)))4 ferric siloxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

tris[bis(trimethylsilyl)amido]iron(III) (22999-67-3,133009-01-5) + (2,6-iPr2C6H3)N(SiMe3)Si(OH)3 (163631-37-6) + trimethylphosphane (594-09-2) → (((PMe3Fe)(O3Si(2,6-iPr2C6H3)N(SiMe3)))4 ferric siloxane (765277-93-8)

Guidance literature:

In hexane; at room temp.; Fe-complex in hexane slowly added to suspn. of silanetriol in the same solvent; mixt. stirred for 72 h; green soln. turned to greenish brown; solvent, hexamethyldisilazane removed in vacuo; recrystn. from THF/toluene=0.05/1 with PMe3 at room temp. for 2 wk; toluene removed by drying under vac.; detd. by IR, ESIMS, elem. anal.;

DOI:10.1002/anie.200453740

upstream raw materials:

tris[bis(trimethylsilyl)amido]iron(III)

(2,6-iPr2C6H3)N(SiMe3)Si(OH)3

trimethylphosphane