Tris[bis(trimethylsilyl)amino]iron(III)

Base Information

Chemical Name:Tris[bis(trimethylsilyl)amino]iron(III)
CAS No.:22999-67-3
Molecular Formula:C₁₈H₅₄FeN₃Si₆
Molecular Weight:537.007
Hs Code.:
Mol file:22999-67-3.mol

Synonyms:

Suppliers and Price of Tris[bis(trimethylsilyl)amino]iron(III)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 3 raw suppliers

Chemical Property of Tris[bis(trimethylsilyl)amino]iron(III)

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Technology Process of Tris[bis(trimethylsilyl)amino]iron(III)

There total 5 articles about Tris[bis(trimethylsilyl)amino]iron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 1070-89-9
sodium hexamethyldisilazane

: 7705-08-0
iron(III) chloride

: 22999-67-3,133009-01-5
tris[bis(trimethylsilyl)amido]iron(III)

Guidance literature:: In benzene; N2; slow addn. of benzene soln. of amide to a suspn. of FeCl3 in benzeneat 4°C (ice bath), warming to room temp, stirring overnight; evapn. to dryness in vac., extn. with n-pentane, filtration, concg. of the filtrate, cooling to -20°C,drying the solid in vac.; concg. ofmother liquor, cooling to -20°C;
DOI:10.1021/ic025825j

Reference yield: 33.0%

: 14760-22-6
iron(II) bis(trimethylsilyl)amide

: 2782-91-4
1,1,3,3-tetramethyl-2-thiourea

: 7704-34-9
sulfur

: 849407-24-5
Fe₂S₂(N(SiMe₃)2)2(tetramethylthiourea)2

: 22999-67-3,133009-01-5
tris[bis(trimethylsilyl)amido]iron(III)

Guidance literature:: In not given; Fe-compound treated with 1 equiv. of S in toluene in the presence of tetramethylthiourea; crystallized from toluene and hexane;
DOI:10.1246/cl.2005.172