(E)-cyclohexane-1,2-diylbis(methylene) bis(4-methylbenzenesulfonate)

Base Information

Chemical Name:(E)-cyclohexane-1,2-diylbis(methylene) bis(4-methylbenzenesulfonate)
CAS No.:62208-94-0
Molecular Formula:C₂₂H₂₈O₆S₂
Molecular Weight:452.593
Hs Code.:
DSSTox Substance ID:DTXSID60504953
NSC Number:281646
Wikidata:Q82359745

Synonyms:62208-94-0;DTXSID60504953;NSC281646;NSC-281646;(E)-cyclohexane-1,2-diylbis(methylene) bis(4-methylbenzenesulfonate);[(1R,2R)-Cyclohexane-1,2-diyl]bis(methylene) bis(4-methylbenzene-1-sulfonate)

Suppliers and Price of (E)-cyclohexane-1,2-diylbis(methylene) bis(4-methylbenzenesulfonate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (E)-cyclohexane-1,2-diylbis(methylene) bis(4-methylbenzenesulfonate)

Chemical Property:

Vapor Pressure:6.2E-14mmHg at 25°C
Boiling Point:604.8°C at 760 mmHg
Flash Point:319.6°C
Density:1.235g/cm³
XLogP3:5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:8
Exact Mass:452.13273096
Heavy Atom Count:30
Complexity:657

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC2CCCCC2COS(=O)(=O)C3=CC=C(C=C3)C
Isomeric SMILES:CC1=CC=C(C=C1)S(=O)(=O)OC[C@@H]2CCCC[C@H]2COS(=O)(=O)C3=CC=C(C=C3)C

Technology Process of (E)-cyclohexane-1,2-diylbis(methylene) bis(4-methylbenzenesulfonate)

There total 8 articles about (E)-cyclohexane-1,2-diylbis(methylene) bis(4-methylbenzenesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.5%

: 65376-05-8,25712-33-8
(+)-(1R,2R)-trans-1,2-bis(hydroxymethyl)cyclohexane

: 98-59-9
p-toluenesulfonyl chloride

: 3205-36-5,7436-01-3,59461-66-4,62208-94-0,76155-28-7,95810-29-0
(R)-trans-1,2-bis-(toluene-4-sulfonyloxymethyl)-cyclohexane

Guidance literature:: With triethylamine; In dichloromethane; at -10 - 0 ℃; for 3h; Concentration;

Reference yield: 58.0%

: 76155-27-6,25712-33-8
(+/-)-trans-2-(hydroxymethyl)cyclohexylmethanol

: 98-59-9
p-toluenesulfonyl chloride

: 3205-36-5,7436-01-3,59461-66-4,62208-94-0,76155-28-7,95810-29-0
trans-1,2-bis(hydroxymethyl)cyclohexane di-p-toluene-sulfonate

Guidance literature:: In pyridine; for 1h; Ambient temperature;

Reference yield:

: 4841-85-4,5048-50-0,13043-60-2,56000-17-0
trans-1,2-bis(ethoxycarbonyl)-4-cyclohexene

: 3205-36-5,7436-01-3,59461-66-4,62208-94-0,76155-28-7,95810-29-0
trans-1,2-bis(hydroxymethyl)cyclohexane di-p-toluene-sulfonate

Guidance literature:: Multi-step reaction with 3 steps

1: H₂ / 5percent Pd/C / ethanol

2: LiAlH₄ / diethyl ether / Heating

3: pyridine / 24 h / 0 °C

With pyridine; lithium aluminium tetrahydride; hydrogen; palladium on activated charcoal; In diethyl ether; ethanol;
DOI:10.1002/mrc.1270160403