((2R,3R)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate

Base Information

Chemical Name:((2R,3R)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate
CAS No.:93221-71-7
Molecular Formula:C₁₁H₂₀O₄S
Molecular Weight:248.343
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ((2R,3R)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate

Chemical Property:

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Technology Process of ((2R,3R)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate

There total 1 articles about ((2R,3R)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 93178-33-7
Methanesulfonic acid (1S,2R)-2-hydroxy-1-methanesulfonyloxymethyl-2,6-dimethyl-hept-5-enyl ester

: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

: 61573-90-8,93221-71-7,93221-74-0,126874-40-6,126874-41-7
((2R,3R)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate

Guidance literature:: With sodium naphthalenide; In tetrahydrofuran;
DOI:10.1016/S0040-4039(01)91166-9

Reference yield:

: 61573-90-8,93221-71-7,93221-74-0,126874-40-6,126874-41-7
((2S,3S)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate

: 126-91-0
linalool

: 126-90-9
(S)-(+)-linalool

Guidance literature:: With naphthalen-1-yl-lithium; In tetrahydrofuran; at -25 ℃; for 0.166667h; Title compound not separated from byproducts.;
DOI:10.1055/s-2008-1032092

Reference yield:

: 61573-90-8,93221-71-7,93221-74-0,126874-40-6,126874-41-7
((2R,3R)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate

: 104322-58-9
2,2-Dimethyl-propionic acid 2-((2R,3R)-3-{(E)-(R)-6-benzenesulfonyl-7-[(R)-2-(tert-butyl-dimethyl-silanyloxy)-1-(2-ethoxy-ethoxy)-ethyl]-4,8-dimethyl-nona-3,8-dienyl}-3-methyl-oxiranyl)-ethyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 67 percent / anhydrous lithium bromide / acetone / 24 h / 23 °C

2: lithium tetrachlorocuprate / tetrahydrofuran

3: potassium hydrogen fluoride, 30percent aqueous hydrogen peroxide / dimethylformamide

4: 85 percent / pyridine / 1 h / 23 °C

5: tert-butyl hydroperoxide / selenium dioxide / CH₂Cl₂ / 24 h / 23 °C

6: 79 percent / carbon tetrachloride, hexamethylphosphorus triamide / diethyl ether / 0.17 h / 0 °C

7: 81 percent / n-butyllithium, 20percent HMPA / 1,2-dimethoxy-ethane / 3 h / from -78 to 0 deg C

With pyridine; tert.-butylhydroperoxide; tetrachloromethane; N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; potassium hydrogen difluoride; dihydrogen peroxide; lithium bromide; selenium(IV) oxide; dilithium tetrachlorocuprate; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1021/ja00280a046