2-(diphenyloxymethyl)azaferrocene

Base Information

• Chemical Name: 2-(diphenyloxymethyl)azaferrocene
• CAS No.: 100329-52-0
• Molecular Formula: C₂₂H₁₉FeNO
• Molecular Weight: 369.246
• Mol file: 100329-52-0.mol

Synonyms:

Chemical Property of 2-(diphenyloxymethyl)azaferrocene

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 2-(diphenyloxymethyl)azaferrocene

There total 1 articles about 2-(diphenyloxymethyl)azaferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

benzophenone (119-61-9) + (η-cyclopentadienyl)(η-pyrrolyl)iron → 2-(diphenyloxymethyl)azaferrocene (100329-52-0)

Guidance literature:

With n-C₄H₉Li; In diethyl ether; (Ar); complex soln. was added dropwise under stirring to n-BuLi soln. at -50°C, stirred for 1 h, then at -20°C for 2 h, allowed to warm to room temp., treated with Ph2CO and water; react. can be conducted in pesence of Me2NC2H2NMe2; water layer extd. (ether), extracts dried (MgSO4), evapd. (vac.), residue dissolved in C6H6, chromd. (SiO2, petroleum ether/ether); recrystn. (hexane/ether); elem. anal.;

DOI:10.1016/0022-328X(85)87276-4

upstream raw materials:

benzophenone