tetraphenylporphyriniron(III) hexafluoroantimonate fluorobenzene solvate

Base Information

• Chemical Name: tetraphenylporphyriniron(III) hexafluoroantimonate fluorobenzene solvate
• CAS No.: 109327-00-6
• Molecular Formula: C₆H₅F*C₄₄H₂₈F₆FeN₄Sb
• Molecular Weight: 1000.42
• Mol file: 109327-00-6.mol

Synonyms:

Chemical Property of tetraphenylporphyriniron(III) hexafluoroantimonate fluorobenzene solvate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphenylporphyriniron(III) hexafluoroantimonate fluorobenzene solvate

There total 2 articles about tetraphenylporphyriniron(III) hexafluoroantimonate fluorobenzene solvate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

silver hexafluoroantimonate (26042-64-8) + fluorobenzene (462-06-6) + tetraphenylporphyrinatoiron(III) bromide (25482-27-3) → tetraphenylporphyriniron(III) hexafluoroantimonate fluorobenzene solvate (109327-00-6)

Guidance literature:

In fluorobenzene; byproducts: AgBr; stirring Fe(C20H8(C6H5)4N4)Br (0.35 mmol) in refluxing fluorobenzene; addn. of solid AgSbF6; refluxing for 30 min; filtering through a fine fritted funnel to remove AgBr;; crystn. on diffusion of hexane into filtrate (5 d);;

Reference yield:

silver hexafluoroantimonate (26042-64-8) + tetraphenylporphyrinatoiron(III) bromide (25482-27-3) → tetraphenylporphyriniron(III) hexafluoroantimonate fluorobenzene solvate (109327-00-6)

Guidance literature:

In fluorobenzene; refluxing of Fe-compd. in fluorobenzene, addn. of solid AgSbF6 (according to K. Shelly et al. Inorg. Chem. 24, 4325 (1985));

DOI:10.1063/1.452552

upstream raw materials:

silver hexafluoroantimonate

tetraphenylporphyrinatoiron(III) bromide

fluorobenzene