1,1'-Bicyclohexyl, 3,3'-dimethyl-

Base Information

• Chemical Name: 1,1'-Bicyclohexyl, 3,3'-dimethyl-
• CAS No.: 103272-52-2
• Molecular Formula: C14H26
• Molecular Weight: 194.36
• Mol file: 103272-52-2.mol

Synonyms:

Chemical Property of 1,1'-Bicyclohexyl, 3,3'-dimethyl-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1'-Bicyclohexyl, 3,3'-dimethyl-

There total 30 articles about 1,1'-Bicyclohexyl, 3,3'-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.5%

4,6-dimethyldibenzothiophene (1207-12-1) → 3,3'-dimethyl-biphenyl (612-75-9) + 3,3'-dimethylbicyclohexyl (103272-52-2) + 1-methyl-3-(3-methylphenyl)cyclohexane + 4,6-dimethyl-1,2,3,4,4a,9b-hexahydrodibenzothiophene + 1,2,3,4-tetrahydro-4,6-dimethyldibenzo[b,d]thiophene (89816-78-4)

Guidance literature:

With hydrogen sulfide; hydrogen; In Hexadecane; at 300 ℃; for 8h; under 54755.5 Torr; Reagent/catalyst; Catalytic behavior; Inert atmosphere;

DOI:10.1016/j.jcat.2013.03.027

Reference yield: 5.8%

4,6-dimethyldibenzothiophene (1207-12-1) → 3,3'-dimethyl-biphenyl (612-75-9) + 3,3'-dimethylbicyclohexyl (103272-52-2) + 1-methyl-3-(3-methylphenyl)cyclohexane

Guidance literature:

With hydrogen; In cyclohexane; at 280 - 300 ℃; for 6h; under 30003 Torr; Reagent/catalyst; Catalytic behavior; Flow reactor;

DOI:10.1016/j.cattod.2020.03.003

Reference yield: 3.1%

3-methylcyclohexyl bromide (13905-48-1) → n-heptane (142-82-5) + 3,3'-dimethylbicyclohexyl (103272-52-2) + methyl cyclohexane (82166-21-0)

Guidance literature:

With hydrogen; In acetone; for 1h; Product distribution; hydrogen-promoted ring-opening reactions of the 3-methylcyclohexyl radical;

DOI:10.1021/ja00094a025

upstream raw materials:

3-methylcyclohexyl bromide

4,6-dimethyldibenzothiophene

1,2,3,4-tetrahydro-4,6-dimethyldibenzo[b,d]thiophene

2-thiocresol