(Z)-2-Butanone oxime

Base Information

• Chemical Name: (Z)-2-Butanone oxime
• CAS No.: 10341-59-0
• Molecular Formula: C4H9NO
• Molecular Weight: 87.1216
• Hs Code.: 2928000090
• Mol file: 10341-59-0.mol

Synonyms:butan-2-one (Z)-oxime;(anti-Methyl)-Butanon-oxim;(Z)-2-butanone oxime;methyl ethyl ketoxime;Z-2-butanone oxime;Z-butan-2-one oxime;

Chemical Property of (Z)-2-Butanone oxime

Chemical Property:

• PSA: 32.59000
• LogP: 1.24650

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-2-Butanone oxime

There total 2 articles about (Z)-2-Butanone oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

butanone (78-93-3) → (Z)-2-butanone oxime (10341-59-0) + (syn-Methyl)-Butanon-oxim (10341-63-6)

Guidance literature:

With pyridine; hydroxylamine hydrochloride; In ethanol; for 12h; optical yield given as %de; Reflux;

DOI:10.1021/jo1011448

Reference yield:

→ (Z)-2-butanone oxime (10341-59-0)

Guidance literature:

Dianion (2), 1.) Methyljodid, 2.) H2O;

DOI:10.1016/S0040-4039(00)71277-9

Reference yield: 75.0%

(Z)-2-butanone oxime (10341-59-0) + diphenyldisulfane (882-33-7) → 3-Phenylsulfanyl-butan-2-one oxime (104260-83-5)

Guidance literature:

With lithium diisopropyl amide; at 0 - 20 ℃; for 1h;

DOI:10.1246/cl.1985.1907

upstream raw materials:

butanone

Downstream raw materials:

3-methyl-6-phenylhex-5-en-2-one oxime

2,4,5-trimethyloxazole

3-Phenylsulfanyl-butan-2-one oxime

N-methylpropanamide

Refernces