bis(2,4-dimethyl-8-quinolinolato)(triphenylsilanolato)aluminum (III)

Base Information

• Chemical Name: bis(2,4-dimethyl-8-quinolinolato)(triphenylsilanolato)aluminum (III)
• CAS No.: 298706-32-8
• Molecular Formula: C₄₀H₃₅AlN₂O₃Si
• Molecular Weight: 646.797
• Mol file: 298706-32-8.mol

Synonyms:

Chemical Property of bis(2,4-dimethyl-8-quinolinolato)(triphenylsilanolato)aluminum (III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis(2,4-dimethyl-8-quinolinolato)(triphenylsilanolato)aluminum (III)

There total 1 articles about bis(2,4-dimethyl-8-quinolinolato)(triphenylsilanolato)aluminum (III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

aluminum isopropoxide (555-31-7) + 8-hydroxy-2,4-dimethylquinoline (115310-98-0) + triphenylhydroxysilane (791-31-1) → bis(2,4-dimethyl-8-quinolinolato)(triphenylsilanolato)aluminum (III) (298706-32-8)

Guidance literature:

In isopropyl alcohol; aluminum isopropoxide in i-PrOH heated to about 100°C for severalmin until solid dissolved; soln. of C9H4N(OH)(CH3)2 in i-PrOH added ove r 0.5 h under reflux; rapid stirred for 1 h; soln. contg. OHSiPh3 and C9H4N(OH)(CH3)2 in i-PrOH added drop ..; ppt. collected by filtration; washed (i-PrOH, Et2O); dried (vac.); elem.anal.;

DOI:10.1016/j.jorganchem.2006.02.002

upstream raw materials:

aluminum isopropoxide

8-hydroxy-2,4-dimethylquinoline

triphenylhydroxysilane