6-Hydroxysugiol

Base Information

Chemical Name:6-Hydroxysugiol
CAS No.:55898-07-2
Molecular Formula:C₂₀H₂₈O₃
Molecular Weight:316.441
Hs Code.:
Mol file:55898-07-2.mol

Synonyms:

Suppliers and Price of 6-Hydroxysugiol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Arctom
6-Hydroxysugiol ≥98%
5mg
$ 566.00

Total 6 raw suppliers

Chemical Property of 6-Hydroxysugiol

Chemical Property:

Boiling Point:478.1±45.0 °C(Predicted)
PKA:8.60±0.70(Predicted)
Density:1.116±0.06 g/cm3(Predicted)

Purity/Quality:

99% ^*data from raw suppliers

6-Hydroxysugiol ≥98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-Hydroxysugiol

There total 17 articles about 6-Hydroxysugiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 70614-86-7
(4aS,10aS)-7-isopropyl-6-methoxy-1,1,4a-trimethyl-1,2,3,4,4a,10a-hexahydrophenanthrene

: 55898-07-2
6α-hydroxy-7-oxoferruginol

Guidance literature:: (4aS,10aS)-7-isopropyl-6-methoxy-1,1,4a-trimethyl-1,2,3,4,4a,10a-hexahydrophenanthrene; With 3,3-dimethyldioxirane; In dichloromethane; acetone; at 25 ℃; for 0.333333h;

With sodium thioethylate; In dichloromethane; N,N-dimethyl-formamide; acetone; at 90 ℃; for 8h;
DOI:10.1016/j.tetlet.2013.06.048

Reference yield: 60.0%

: 70614-86-7
(4aS,10aS)-7-isopropyl-6-methoxy-1,1,4a-trimethyl-1,2,3,4,4a,10a-hexahydrophenanthrene

: 55898-07-2
6α-hydroxy-7-oxoferruginol

: 140923-35-9
6-Hydroxy-5,6-dehydrosugiol

Guidance literature:: (4aS,10aS)-7-isopropyl-6-methoxy-1,1,4a-trimethyl-1,2,3,4,4a,10a-hexahydrophenanthrene; With 3,3-dimethyldioxirane; In dichloromethane; acetone; at 25 ℃; for 1h;

With sodium thioethylate; In dichloromethane; N,N-dimethyl-formamide; acetone; at 90 ℃; for 8h;
DOI:10.1016/j.tetlet.2013.06.048

Reference yield:

: 79593-19-4
(+)-(4aS,10aS)-6-acetyl-7-isopropyl-1,1,4a-trimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene

: 55898-07-2
6α-hydroxy-7-oxoferruginol

: 140923-35-9
6-Hydroxy-5,6-dehydrosugiol

Guidance literature:: Multi-step reaction with 7 steps

1.1: 3-chloro-benzenecarboperoxoic acid; toluene-4-sulfonic acid / 1,2-dichloro-ethane / 5 h / Reflux

2.1: potassium carbonate / dichloromethane; methanol / 2 h / 0 °C

3.1: lithium hydroxide / N,N-dimethyl-formamide / 4 h / 20 °C / Inert atmosphere

3.2: 0.75 h / 0 °C

4.1: chromium(VI) oxide; acetic acid / 4 h / 20 °C

5.1: sodium tetrahydroborate / methanol / 12 h / 20 °C / Inert atmosphere

6.1: methanesulfonyl chloride; triethylamine / dichloromethane / 12 h / 0 °C / Inert atmosphere

7.1: 3,3-dimethyldioxirane / dichloromethane; acetone / 1 h / 25 °C

7.2: 8 h / 90 °C

With chromium(VI) oxide; sodium tetrahydroborate; 3,3-dimethyldioxirane; potassium carbonate; toluene-4-sulfonic acid; acetic acid; methanesulfonyl chloride; triethylamine; 3-chloro-benzenecarboperoxoic acid; lithium hydroxide; In methanol; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide; acetone; 1.1: |Baeyer-Villiger Ketone Oxidation;
DOI:10.1016/j.tetlet.2013.06.048