MeP(p-CF₃Ph)₂(BH₃)

Base Information

• Chemical Name: MeP(p-CF₃Ph)₂(BH₃)
• CAS No.: 591216-46-5
• Molecular Formula: C₁₅H₁₄BF₆P
• Molecular Weight: 350.051
• Mol file: 591216-46-5.mol

Synonyms:

Chemical Property of MeP(p-CF₃Ph)₂(BH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of MeP(p-CF₃Ph)₂(BH₃)

There total 1 articles about MeP(p-CF₃Ph)₂(BH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

borane-THF (14044-65-6) + C15H11F6P (591216-45-4) → MeP(p-CF3Ph)2(BH3) (591216-46-5)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ic4028223

Reference yield: 80.0%

diethyl ether (60-29-7,927820-24-4) + MeP(p-CF3Ph)2(BH3) (591216-46-5) + phenylborondichloride (873-51-8) + sec.-butyllithium (598-30-1) → [PhB{CH2P(p-CF3Ph)2(BH3)}3]Li(Et2O) (1595138-51-4)

Guidance literature:

diethyl ether; MeP(p-CF₃Ph)₂(BH₃); sec.-butyllithium; at -78 ℃; for 3h; Inert atmosphere; Schlenk technique;

phenylborondichloride; In toluene; at -78 - 20 ℃; for 14h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic4028223

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + MeP(p-CF3Ph)2(BH3) (591216-46-5) + diphenylboronchloride (3677-81-4) → [(phenyl)2B(CH2P(p-CF3C6H4)2(BH3))2][Li(THF)(x)]

Guidance literature:

With sec-butyllithium; In diethyl ether; cyclohexane; glovebox; addn. of sec-butyllithium dissolved in cyclohexane to ether soln. of CH3P(C6H4CF3)2(BH3) at -78°C (stirring), stirring at this temp. for 3 h, addn. of toluene soln. of (C6H5)2BCl, warming up over 12 h with stirring, evapn., addn of THF; volatiles removal under reduced pressure, washing with petroleum ether, dissolving in diethyl ether, filtration (Celite), volatiles removal under reduced pressure;

DOI:10.1021/ic034150x

upstream raw materials:

borane-THF

C₁₅H₁₁F₆P

Downstream raw materials:

[PhB{CH₂P(p-CF₃Ph)₂(BH₃)}₃]Li(Et₂O)