ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2

Base Information

Chemical Name:ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2
CAS No.:113605-52-0
Molecular Formula:C₅₂H₄₄ClO₂P₄Re
Molecular Weight:1046.48
Hs Code.:

ReCl(CO)2((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)2

Synonyms:

Suppliers and Price of ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2

There total 1 articles about ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 14099-01-5
rhenium(I) pentacarbonyl chloride

: 2071-20-7
bis-diphenylphosphinomethane

: 113605-52-0
ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2

Guidance literature:: In 1,3,5-trimethyl-benzene; a soln. of Re-complex and dppm in mesitylene was refluxed for 9 h; the soln. was allowed to cool; elem. anal.;
DOI:10.1039/DT9870001763

Reference yield: 92.0%

: 113605-52-0
ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2

: 420-37-1
trimethoxonium tetrafluoroborate

: ReCl(CO)2(C₆H₅)2PCH₂P(C₆H₅)2((C₆H₅)2PCH₂P(C₆H₅)2CH₃)⁽¹⁺⁾*BF₄^(1-)=ReCl(CO)2((C₆H₅)2PCH₂(C₆H₅)2P(C₆H₅)2PCH₂P(C₆H₅)2CH₃)BF₄

Guidance literature:: In dichloromethane; (OMe3)BF4 was added to a soln. of Re-complex in CH2Cl2, the mixt. was stirred for 3 h; filtered, the filtrate was evapd. to dryness, the residue was triturated with Et2O; elem. anal.;
DOI:10.1039/DT9870001763

Reference yield: 71.0%

: ammonium hexafluorophosphate

: di(rhodium)tetracarbonyl dichloride

: 113605-52-0
ReCl(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)2

: Re(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2ClRh(CO)⁽¹⁺⁾*PF₆^(1-)*0.33CH₂Cl₂=Re(CO)3(P(C₆H₅)2CH₂P(C₆H₅)2)2ClRh(CO)PF₆*0.33CH₂Cl₂

Guidance literature:: With CH₂Cl₂; In methanol; dichloromethane; Rh-complex was added to a soln. of Re-complex in CH2Cl2, the soln. was then treated with a soln. of NH4PF6 in MeOH, the mixt. was stirred for 1 h under an atmosphere of CO; evapn. to dryness under vac.; extn. with CH2Cl2; recrystn. from CH2Cl2-n-hexane; elem. anal.;
DOI:10.1039/DT9870001763