zirconium fluoride monohydrate

Base Information

• Chemical Name: zirconium fluoride monohydrate
• CAS No.: 14596-11-3
• Molecular Formula: F₄Zr*H₂O
• Molecular Weight: 185.233
• Mol file: 14596-11-3.mol

Synonyms:

Chemical Property of zirconium fluoride monohydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zirconium fluoride monohydrate

There total 3 articles about zirconium fluoride monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

uranium hexafluoride (7783-81-5) + (Ca0.15Zr0.85)O1.85 → calcium fluoride + uranyl fluoride + zirconium fluoride monohydrate (14596-11-3,867143-63-3,15298-38-1) + uranium(IV) tetrafluoride (10049-14-6) + uranium oxide

Guidance literature:

In neat (no solvent); byproducts: O2, UO2F2*1.5H2O, ZrO0.46F3.08; ZrO0.67F2.67; samples of alumina in alumina boat exposed to UF6 (20-22.7 kPa) in reaction chamber (alumina, electric tube furnace) at 973-1473 K for 20 min to 4 h; X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy;

Reference yield:

ammonium acetate (92206-38-7) + zirconyl chloride octahydrate + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → zirconium fluoride monohydrate (14596-11-3,867143-63-3,15298-38-1)

Guidance literature:

With acetic acid; ammonium pyrrolidinedithiocarbamate (APDC); 4-methyl-2-pentanone (MIBK); In water; Sonication; to Zr soln. was added buffer (aq. ammonium acetate, acetic acid, pH ca.4.5), soln. was filtered at room temp., 1% APDC and 35 mL MIBK were added, soln. was shaken for 1 min, aq. phase was collected, extraction (PH=2.5) repeated three times, HF was added; water was added to ppt., slurry was sonicated for 1 h, water was decanted, washing procedure was repeated three times, ppt. was dried in beaker at 190°C, then decomposed at 370°C;

DOI:10.1111/j.1551-2916.2011.04641.x

Reference yield:

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + zirconium(IV) oxide (7440-67-7) → zirconium fluoride monohydrate (14596-11-3,867143-63-3,15298-38-1)

Guidance literature:

In hydrogen fluoride; aq. HF; treating ZrO2 with boiling hydrofluoric acid; slow evapn. of sand bath;

DOI:10.1002/zaac.200700465

upstream raw materials:

uranium hexafluoride

hydrogen fluoride

zirconium(IV) oxide

ammonium acetate

Downstream raw materials:

zirconium(IV) fluoride

zirconium(IV) oxide

hydrogen fluoride

water