Zirconium

Base Information

• Chemical Name: Zirconium
• CAS No.: 7440-67-7
• Deprecated CAS: 141631-74-5,141631-75-6,141631-77-8,182260-46-4,1864797-49-8,141631-75-6,141631-77-8,182260-46-4
• Molecular Formula: Zr
• Molecular Weight: 91.224
• Hs Code.: 2615100000
• European Community (EC) Number: 231-176-9,933-703-4
• ICSC Number: 1405
• UN Number: 1358,2008,1932,1308,2858,2009
• UNII: C6V6S92N3C
• DSSTox Substance ID: DTXSID0049818
• Wikipedia: Zirconium
• Wikidata: Q1038
• RXCUI: 1534771
• Mol file: 7440-67-7.mol

Synonyms:Zirconium

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Chemical Property of Zirconium

Chemical Property:

• Appearance/Colour: blue-black Solid
• Melting Point: 1852 °C(lit.)
• Boiling Point: 4377 °C(lit.)
• PSA: 0.00000
• Density: 1.01 g/mL at 25 °C
• LogP: 0.00000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 89.904699
• Heavy Atom Count: 1
• Complexity: 0
• Transport DOT Label: Flammable Solid,Spontaneously Combustible,Flammable Liquid

Purity/Quality:

Safty Information:

• Pictogram(s): F, C
• Hazard Codes: F, C

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [Zr]
• Recent NIPH Clinical Trials: A Comparative Study of Improvement of Hyperkalemia by Sodium Zirconium Cyclosilicate Hydrate and Polystyrene Sulfonate Calcium in Chronic Hemodialysis Patients (Multicenter collaborative study)
• Inhalation Risk: A harmful concentration of airborne particles can be reached quickly when dispersed.
• Effects of Short Term Exposure: May cause mechanical irritation to the eyes.
• Effects of Long Term Exposure: Repeated or prolonged inhalation of dust particles may cause effects on the lungs.

Technology Process of Zirconium

There total 624 articles about Zirconium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

zirconium(IV) chloride (10026-11-6) + magnesium (7439-95-4) → zirconium (7440-67-7) + magnesium chloride (7786-30-3)

Guidance literature:

In melt; heating at 800°C under inert gas in a closed vessel, Kroll-process; apparatus described;; separation of Mg and MgCl2 by vacuum destillation;;

Reference yield:

ZrO(2+)*2Cl(1-)*ZrO2=ZrOCl2*ZrO2 → zirconium(IV) chloride (10026-11-6) + zirconium(IV) oxide (7440-67-7)

Guidance literature:

In neat (no solvent); decomposition at temp. higher than 600°C;;

Reference yield:

zirconium chloride (13762-26-0) → zirconium (7440-67-7) + zirconium(IV) chloride (10026-11-6) + zirconium(IV) oxide (7440-67-7)

Guidance literature:

In neat (no solvent); heating at temp. higher than 500°C in closed quartz tube;;

upstream raw materials:

zirconyl chloride

water

calcium chloride

calcium(II) nitrate

Downstream raw materials:

2-(ethylthio)phenol

chromium

zirconium(IV) iodide

zirconium(IV) bromide

Refernces

• 1、 Nam, Seok-Woo,Yoo, Jung-Ho,Nam, Suheun,Ko, Dae-Hong,Yang, Cheol-Woong,Ku, Ja-Hum. "Characteristics of ZrO2 films with Al and Pt gate electrodes". . p. G849-G853. Retrieved 2003.
• 2、 Tsuchiya, Hiroaki,MacAk, Jan M.,Taveira, Luciano,Schmuki, Patrik. "Fabrication and characterization of smooth high aspect ratio zirconia nanotubes". . p. 188 - 191. Retrieved 2005.
• 3、 Miyazawa,Suzuki,Wey. "Microstructure and oxidation-resistant property of sol-gel derived ZrO2-Y2O3 films prepared on austenitic stainless steel substrates". . p. 347 - 355. Retrieved 1995.
• 4、 Bell,Jung. "An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over zirconia". . p. 339 - 347. Retrieved 2001.
• 5、 Diaz-Torres,De la Rosa,Salas,Romero,Angeles-Chavez. "Efficient photoluminescence of Dy3+ at low concentrations in nanocrystalline ZrO2". . p. 75 - 80. Retrieved 2008.
• 6、 Audry,Hoggan,Saussey,Lavalley,Lauron-Pernot,Le Govic. "Infrared Study and Quantum Calculations of the Conversion of Methylbutynol into Hydroxymethylbutanone on Zirconia". . p. 471 - 481. Retrieved 1997.
• 7、 Manivasakan, Palanisamy,Rajendran, Venkatachalam,Ranjan Rauta, Prema,Bandhu Sahu, Bhakta,Krushna Panda, Bharati. "Synthesis of monoclinic and cubic ZrO2 nanoparticles from zircon". . p. 1410 - 1420. Retrieved 2011.
• 8、 Bhatia, B. M. L.,Sawhney, S. S.. "". . p. 363 - 366. Retrieved 1981.
• 9、 Ma, Yanfu,Xu, Guangyue,Wang, Hao,Wang, Yingxiong,Zhang, Ying,Fu, Yao. "Cobalt Nanocluster Supported on ZrREnOx for the Selective Hydrogenation of Biomass Derived Aromatic Aldehydes and Ketones in Water". . p. 1268 - 1277. Retrieved 2018.
• 10、 Zhou, Qianxue,Dai, Mingxing,Wang, Renhui,Jin, Lei,Zhu, Shijian,Qian, Liang,Wu, Yanmei,Feng, Jiwen. "Enhanced room-temperature magnetoresistance in high-temperature sintered La2/3Sr1/3MnO3 doped with ZrO2". . p. 206 - 211. Retrieved 2007.