RhCl(P(C₆H₅)3)2((C₆H₅)2PO₂CCHC(CH₃)2)

Base Information

Chemical Name:RhCl(P(C₆H₅)3)2((C₆H₅)2PO₂CCHC(CH₃)2)
CAS No.:128110-78-1
Molecular Formula:C₅₃H₄₇ClO₂P₃Rh
Molecular Weight:947.235
Hs Code.:

RhCl(P(C<sub>6</sub>H<sub>5</sub>)3)2((C<sub>6</sub>H<sub>5</sub>)2PO<sub>2</sub>CCHC(CH<sub>3</sub>)2)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of RhCl(P(C₆H₅)3)2((C₆H₅)2PO₂CCHC(CH₃)2)

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Technology Process of RhCl(P(C₆H₅)3)2((C₆H₅)2PO₂CCHC(CH₃)2)

There total 2 articles about RhCl(P(C₆H₅)3)2((C₆H₅)2PO₂CCHC(CH₃)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 14694-95-2
Wilkinson's catalyst

: 104229-88-1
Ph₂PO₂CCH=CMe₂

: 128110-78-1,105796-10-9
chloro(diphenylphosphino 3-methylbut-2-enoate)bis(triphenylphosphine)rhodium(I)

Guidance literature:: In tetrahydrofuran; Addn. of a soln. of Ph2PO2CCHCMe2 in THF to a suspension of RhCl(PPh3)3 in THF, after stirring for 5 min evapn. of the soln. to 2 ml to give a bright orange crystalline solid; Solid of RhCl(PPh3)2(Ph2PO2CCHCMe2 is collected, washed with light petroleum and dried in vacuo, a second crop of crystals is obtd. from the filtrate by addn. of excess light petroleum, the combined solid are recrystd. from CH2Cl2/light petroleum;
DOI:10.1039/DT9900000029

Reference yield:

: 14694-95-2
Wilkinson's catalyst

: 104229-88-1
Ph₂PO₂CCH=CMe₂

: 128110-78-1,105796-10-9
RhCl(P(C₆H₅)3)2((C₆H₅)2PO₂CCHC(CH₃)2)

Guidance literature:: In not given; react. of Rh-complex with 1 equiv of ligand;
DOI:10.1039/c39860000977

Reference yield: 67.0%

: 16893-92-8
potassium hexafluoroantimonate

: 128110-78-1,105796-10-9
chloro(diphenylphosphino 3-methylbut-2-enoate)bis(triphenylphosphine)rhodium(I)

: 128025-11-6
diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) hexafluoroantimonate

Guidance literature:: In tetrahydrofuran; A suspension of RhCl(PPh3)2(Ph2PO2CCHCMe2) and KSbF6 in THF is stirred for 3 h; Yellow prod. of Rh(PPh3)2(Ph2PO2CCHCMe2)SbF6 is pptd. from the THF soln. with excess of diethyl ether and recrystd. from CH2Cl2/diethyl ether;
DOI:10.1039/DT9900000029