diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) tetrafluoroborate

Base Information

Chemical Name:diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) tetrafluoroborate
CAS No.:128025-10-5
Molecular Formula:BF₄*C₅₃H₄₇O₂P₃Rh
Molecular Weight:998.586
Hs Code.:

Synonyms:

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Chemical Property of diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) tetrafluoroborate

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Technology Process of diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) tetrafluoroborate

There total 3 articles about diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 14104-20-2
silver tetrafluoroborate

: 128110-78-1,105796-10-9
chloro(diphenylphosphino 3-methylbut-2-enoate)bis(triphenylphosphine)rhodium(I)

: 128025-10-5
diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) tetrafluoroborate

Guidance literature:: In dichloromethane; byproducts: AgCl; A suspension of RhCl(PPh3)2(Ph2PO2CCHCMe2) and AgBF4 in CH2Cl2 is stirred for 30 min., formed soln. is filtered from the AgCl ppt.and evapd. to 2 ml, on addn. of small portions of diethyl ether a crystalline material is formed; Crystalline material of Rh(PPh3)2(Ph2PO2CCHCMe2)BF4 is collected, washed with diethyl ether, dried in vacuo and recrystd. from acetone/diethyl ether;
DOI:10.1039/DT9900000029

Reference yield:

: 104229-88-1
Ph₂PO₂CCH=CMe₂

: 128025-10-5
diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) tetrafluoroborate

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: dichloromethane

In tetrahydrofuran; dichloromethane;
DOI:10.1039/DT9900000029

Reference yield:

: 14694-95-2
Wilkinson's catalyst

: 128025-10-5
diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) tetrafluoroborate

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: dichloromethane

In tetrahydrofuran; dichloromethane;
DOI:10.1039/DT9900000029