hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel

Base Information

Chemical Name:hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel
CAS No.:1161924-31-7
Molecular Formula:C₄₅H₄₁NiP₃S
Molecular Weight:765.498
Hs Code.:

Synonyms:

Suppliers and Price of hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel

There total 1 articles about hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 28069-69-4
tetrakis(trimethylphosphine)nickel⁽⁰⁾

: 1161924-37-3
(3-diphenylphosphanyl)-2-thionaphthol

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 1161924-31-7
hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel

Guidance literature:: In tetrahydrofuran; byproducts: trimetylphosphine; combining of soln. of Ni(PMe3)4 in THF containing excess trimethylphosphine with (2-diphenylphosphanyl)thiophenol; stirring for 5 min; addn. of 1,3-bis(diphenylphosphanyl)propane in THF; removal of volatiles in vac., washing with pentane; drying in vac., elem. anal.;
DOI:10.1016/j.jorganchem.2009.01.023

Reference yield: 64.0%

: 1161924-31-7
hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel

: 15629-49-9
bis(1,3-bis(diphenylphosphino)propane)nickel⁽⁰⁾

: 14897-21-3,138917-09-6
bis(2-diphenylphosphanyl)thiophenolato[P,S]nickel

Guidance literature:: In tetrahydrofuran; byproducts: dihydrogen; for 20 min at 20°C according to: P.W. Jolly, G. Wilke, The Organic Chemistry of Nickel, Academic Press, New York, 1974, p. 106;
DOI:10.1016/j.jorganchem.2009.01.023

Reference yield:

: 1161924-31-7
hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel

: 1161924-36-2
(2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: tetrahydrofuran

In tetrahydrofuran;
DOI:10.1016/j.jorganchem.2009.01.023