(2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel

Base Information

Chemical Name:(2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel
CAS No.:1161924-36-2
Molecular Formula:C₂₄H₃₂NiP₃S
Molecular Weight:504.195
Hs Code.:

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Chemical Property of (2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel

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Technology Process of (2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel

There total 6 articles about (2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 926319-61-1
hydrido(2-diphenylphosphanyl)thiophenolato[P,S]bis(trimethylphosphine)nickel

: 594-09-2
trimethylphosphane

: 1161924-36-2
(2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel

Guidance literature:: In diethyl ether; byproducts: dihydrogen; (Ar); dissolving of Ni(PMe3)2(H)(PPh2C6H4S) in Et2O containing of PMe3 at -10°C; keeping at this temp. for 2 h; filtration, cooling to -27°C; crystn.;
DOI:10.1016/j.jorganchem.2009.01.023

Reference yield: 12.0%

: 28069-69-4
tetrakis(trimethylphosphine)nickel⁽⁰⁾

: 14897-21-3,138917-09-6
bis(2-diphenylphosphanyl)thiophenolato[P,S]nickel

: 594-09-2
trimethylphosphane

: 1161924-36-2
(2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel

Guidance literature:: In tetrahydrofuran; combining of Ni(PMe3)4 in THF containing of PMe3 with Ni(PPh2C6H4S)2; stirring for 3 h at -10°C; evapn. of volatiles; extn. with Et2O containing of PMe3; crystn. at -27°C;
DOI:10.1016/j.jorganchem.2009.01.023

Reference yield: 12.0%

: 28069-69-4
tetrakis(trimethylphosphine)nickel⁽⁰⁾

: 119327-17-2
(2-mercaptophenyl)diphenylphosphine

: 594-09-2
trimethylphosphane

: 14897-21-3,138917-09-6
bis(2-diphenylphosphanyl)thiophenolato[P,S]nickel

: 1161924-36-2
(2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel

Guidance literature:: In diethyl ether; byproducts: dihydrogen; combining of soln. of Ni(PMe)4 in Et2O containing of PMe3 with (3-diphenylphosphanyl)-2-thionaphthol; stirring for 60 min at -50°C; filtration at -50°C; warming to -10°C; keeping at this temp. for 2 h; evolution of gas and pptn., filtration at -10°C; cooling to -27°C; crystn.;
DOI:10.1016/j.jorganchem.2009.01.023