W(CO)4(P(OC₆H₅)3)C(SCH₃)2

Base Information

Chemical Name:W(CO)4(P(OC₆H₅)3)C(SCH₃)2
CAS No.:77826-93-8
Molecular Formula:C₂₅H₂₁O₇PS₂W
Molecular Weight:712.393
Hs Code.:

W(CO)4(P(OC<sub>6</sub>H<sub>5</sub>)3)C(SCH<sub>3</sub>)2

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Chemical Property of W(CO)4(P(OC₆H₅)3)C(SCH₃)2

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Technology Process of W(CO)4(P(OC₆H₅)3)C(SCH₃)2

There total 1 articles about W(CO)4(P(OC₆H₅)3)C(SCH₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 74-93-1
methylthiol

: 65969-60-0
W(CO)4(P(OC₆H₅)3)CS

: 65969-60-0,66007-56-5
W(CO)4(P(OC₆H₅)3)CS

: 7646-69-7
sodium hydride

: 77826-93-8
W(CO)4(P(OC₆H₅)3)C(SCH₃)2

Guidance literature:: With methyl iodide; In tetrahydrofuran; ligand was bubbled through a suspn. of NaH in THF for 30 min, soln. wasstirred for 30 min under N2, mixt. of W-complexes in THF was added, stirred for 15 min, CH3I was added, stirred for 15 min; evapd. to dryness, residue extd. with hexane, extract was evapd. to dryness, residue was taken up in CS2, placed on Florisil column, eluted with CS2; elem. anal.;
DOI:10.1021/ic50223a044

Reference yield: 73.0%

: 77826-93-8
W(CO)4(P(OC₆H₅)3)C(SCH₃)2

: 100-46-9
benzylamine

: 77827-01-1
W(CO)4P(OC₆H₅)3CNCH₂C₆H₅

Guidance literature:: In hexane; to soln. of W-complex in hexane ligand was added, stirred for 12 h under N2 at room temp.; evapd. to dryness under reduced pressure, crystd. from hexane at -20°C; elem. anal.;
DOI:10.1021/ic50223a044

Reference yield: 64.0%

: 77826-93-8
W(CO)4(P(OC₆H₅)3)C(SCH₃)2

: 109-76-2,54018-94-9
Trimethylenediamine

: 77827-06-6
W(CO)4P(OC₆H₅)3CN(CH₂)3NH₂

Guidance literature:: In hexane; dichloromethane; to soln. of W-complex in hexane was added ligand, CH2Cl2 was added, stirred for 10 min under N2; evapd. to dryness, residue was taken up in CS2, placed on alumina column, crystd. from hexane at -20°C;
DOI:10.1021/ic50223a044