dichloro-(1-ethyl-2-(p-tolylazo)imidazole)platinum(II)

Base Information

• Chemical Name: dichloro-(1-ethyl-2-(p-tolylazo)imidazole)platinum(II)
• CAS No.: 338948-79-1
• Molecular Formula: C₁₂H₁₄Cl₂N₄Pt
• Molecular Weight: 480.256
• Mol file: 338948-79-1.mol

Synonyms:

Chemical Property of dichloro-(1-ethyl-2-(p-tolylazo)imidazole)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro-(1-ethyl-2-(p-tolylazo)imidazole)platinum(II)

There total 1 articles about dichloro-(1-ethyl-2-(p-tolylazo)imidazole)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + 1-ethyl-2-(4-methylphenylazo)imidazole (198347-70-5) → dichloro-(1-ethyl-2-(p-tolylazo)imidazole)platinum(II) (338948-79-1)

Guidance literature:

In water; acetonitrile; ligand in MeCN/H2O added dropwise to MeCN/H2O soln. of K2PtCl4, refluxedfor 48 h; pptd. on slow evapn., filtered, washed with cold MeCN/H2O, dried, dissolved in min. vol. of CH2Cl2, chromd. (SiO2, C6H6/MeCN); elem. anal.;

DOI:10.1016/S0020-1693(00)00311-X

Reference yield:

dichloro-(1-ethyl-2-(p-tolylazo)imidazole)platinum(II) (338948-79-1) + benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9) → (catecholato)(1-ethyl-2-(p-tolylazo)imidazole)platinum(II) (338948-85-9)

Guidance literature:

With (C₂H₅)3N; In methanol; chloroform; (N2); ligand in MeOH added to Pt complex in CHCl3/MeOH, Et3N added, stirred; concd. (N2), ppt. filtered, washed (cold MeOH), dried (vac.), dissolved in a min. vol. of CH2Cl2, chromd. (SiO2, C6H6/MeCN), evapd.; elem. anal.;

DOI:10.1016/S0020-1693(00)00311-X

Reference yield:

dichloro-(1-ethyl-2-(p-tolylazo)imidazole)platinum(II) (338948-79-1) + o-chloranil (1198-55-6) → (tetrachlorocatecholato)(1-ethyl-2-(p-tolylazo)imidazole)platinum(II) (338948-88-2)

Guidance literature:

With (C₂H₅)3N; In methanol; chloroform; (N2); ligand in MeOH added to Pt complex in CHCl3/MeOH, Et3N added, stirred; concd. (N2), ppt. filtered, washed (cold MeOH), dried (vac.), dissolved in a min. vol. of CH2Cl2, chromd. (SiO2, C6H6/MeCN), evapd.; elem. anal.;

DOI:10.1016/S0020-1693(00)00311-X

upstream raw materials:

potassium tetrachloroplatinate(II)

1-ethyl-2-(4-methylphenylazo)imidazole

Downstream raw materials:

(catecholato)(1-ethyl-2-(p-tolylazo)imidazole)platinum(II)

(tetrachlorocatecholato)(1-ethyl-2-(p-tolylazo)imidazole)platinum(II)

(4-tert-butylcatecholato)(1-ethyl-2-(p-tolylazo)imidazole)platinum(II)

(3,5-di-tert-butylcatecholato)(1-ethyl-2-(p-tolylazo)imidazole)platinum(II)