[bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV)

Base Information

Chemical Name:[bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV)
CAS No.:116232-52-1
Molecular Formula:C₁₆H₁₃Cl₂PZr
Molecular Weight:398.383
Hs Code.:

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Chemical Property of [bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV)

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Technology Process of [bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV)

There total 3 articles about [bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 21959-01-3,125410-70-0,125410-71-1
zirconium tetrachloride bis(tetrahydrofuran) complex

: 116232-60-1
(phenylphosphino)(cyclopentadienylthallium)2

: 55172-29-7,7791-12-0
thallium chloride

: 116232-52-1
[bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV)

Guidance literature:: In tetrahydrofuran; Addn. of THF to the starting materials, stirring of mixt. overnight (room temp., Ar).; Filtn., washing of TlCl with THF, evapn. of pale orange soln. to dryness and washing of residue with pentane. Elem. anal.;
DOI:10.1021/om00101a006

Reference yield: 78.0%

: 21959-01-3,125410-70-0,125410-71-1
zirconium tetrachloride bis(tetrahydrofuran) complex

: 116232-60-1
(TlC₅H₄)2P(C₆H₅)

: 116232-52-1
[bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV)

Guidance literature:: In tetrahydrofuran; byproducts: TlCl;
DOI:10.1016/S0020-1693(00)80646-5

Reference yield:

: dilithium phenylbis(cyclopentadienyl)phosphane

: 10026-11-6
zirconium(IV) chloride

: 116232-52-1
[bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV)

Guidance literature:: In tetrahydrofuran; toluene; Li-compd. and ZrCl4 placed in a Schlenk flask, toluene added, cooled to 213 K, THF added, warmed to room temp. overnight; filtered, solv. removed in vac., filtered, filtrate cooled to 248 K, stored for 2 d;
DOI:10.1107/S0108270110004531