nickel(II) bis(2-mercapto-3-trimethylsilylphenyl)sulfide PCy₃

Base Information

• Chemical Name: nickel(II) bis(2-mercapto-3-trimethylsilylphenyl)sulfide PCy₃
• CAS No.: 472958-14-8
• Molecular Formula: C₃₆H₅₇NiPS₃Si₂
• Molecular Weight: 731.881
• Mol file: 472958-14-8.mol

Synonyms:

Chemical Property of nickel(II) bis(2-mercapto-3-trimethylsilylphenyl)sulfide PCy₃

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of nickel(II) bis(2-mercapto-3-trimethylsilylphenyl)sulfide PCy₃

There total 1 articles about nickel(II) bis(2-mercapto-3-trimethylsilylphenyl)sulfide PCy₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

Ni3(S(C6H3S(Si(CH3)3))2)3 (472958-11-5) + tricyclohexylphosphine (2622-14-2) → nickel(II) bis(2-mercapto-3-trimethylsilylphenyl)sulfide PCy3 (472958-14-8)

Guidance literature:

In tetrahydrofuran; under dry N2 at room temp., THF-soln. of P-compd. was added to THF-soln.of Ni-compd., stirring for 3 h; soln. was filtered, concd., layered with MeOH, ppt. was sepd. after 3 d,washed with MeOH, dried in vac., elem. anal.;

DOI:10.1002/1099-0682(200208)2002:8<2138::AID-EJIC2138>3.0.CO;2-H

Reference yield:

chloroform-d1 (865-49-6) + nickel(II) bis(2-mercapto-3-trimethylsilylphenyl)sulfide PCy3 (472958-14-8) → Ni(S(C6H3S(Si(CH3)3))2)(P(C6H11)3)*2C(2)HCl3

Guidance literature:

In tetrahydrofuran; methanol; crystn. for 3-5 d at -20 °C;

DOI:10.1002/1099-0682(200208)2002:8<2138::AID-EJIC2138>3.0.CO;2-H

upstream raw materials:

Ni₃(S(C₆H₃S(Si(CH₃)3))2)3

tricyclohexylphosphine