[Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]ClO₄

Base Information

• Chemical Name: [Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]ClO₄
• CAS No.: 301647-76-7
• Molecular Formula: C₇₅H₆₁OP₄Pt*ClO₄
• Molecular Weight: 1396.73
• Mol file: 301647-76-7.mol

Synonyms:

Chemical Property of [Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]ClO₄

There total 1 articles about [Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₆H₄P(C₆H₅)2CHCOCHP(C₆H₅)3)(P(C₆H₅)3)2]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

[Pt((C6H4)P(C6H5)2CHCOCH2P(C6H5)3)(NCCH3)2](2+)*2ClO4(1-)=[Pt((C6H4)P(C6H5)2CHCOCH2P(C6H5)3)(NCCH3)2](ClO4)2 + triphenylphosphine (603-35-0) → [Pt(C6H4P(C6H5)2CHCOCHP(C6H5)3)(P(C6H5)3)2](1+)*ClO4(1-)=[Pt(C6H4P(C6H5)2CHCOCHP(C6H5)3)(P(C6H5)3)2]ClO4 (301647-76-7)

Guidance literature:

With sodium hydride; In tetrahydrofuran; byproducts: H2, NCCH3, NaClO4; excess of P(C6H5)3 added to suspn. of Pt complex in THF, NaH (excess) added, mixt. stirred at 25°C overnight; filtered, filtrate evapd. to dryness, extd. with CH2Cl2, filtered, soln.evapd. to dryness, solid collected with Et2O, dried on air; elem. anal.;

DOI:10.1039/b002848g

Reference yield: 69.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + [Pt(C6H4P(C6H5)2CHCOCHP(C6H5)3)(P(C6H5)3)2](1+)*ClO4(1-)=[Pt(C6H4P(C6H5)2CHCOCHP(C6H5)3)(P(C6H5)3)2]ClO4 (301647-76-7) → Pt(C6H4P(C6H5)2CHCOCH(P(C6H5)3)AuCl)(P(C6H5)3)2(1+)*ClO4(1-)=[Pt(C6H4P(C6H5)2CHCOCH(P(C6H5)3)AuCl)(P(C6H5)3)2]ClO4

Guidance literature:

In dichloromethane; byproducts: S(CH2)4; ClAuS(CH2)4 added to soln. of Pt complex in CH2Cl2, stirred at 25°C for 15 min; evapd. to dryness, residue treated with Et2O;

DOI:10.1039/b002848g

upstream raw materials:

triphenylphosphine