dichloro(2,4-di-tert-butyl-6-piperidin-1-ylmethyl-phenolato)(η5-cylopentadienyl)titanium

Base Information

• Chemical Name: dichloro(2,4-di-tert-butyl-6-piperidin-1-ylmethyl-phenolato)(η5-cylopentadienyl)titanium
• CAS No.: 514791-78-7
• Molecular Formula: C₂₅H₃₇Cl₂NOTi
• Molecular Weight: 486.361
• Mol file: 514791-78-7.mol

Synonyms:

Chemical Property of dichloro(2,4-di-tert-butyl-6-piperidin-1-ylmethyl-phenolato)(η5-cylopentadienyl)titanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro(2,4-di-tert-butyl-6-piperidin-1-ylmethyl-phenolato)(η5-cylopentadienyl)titanium

There total 1 articles about dichloro(2,4-di-tert-butyl-6-piperidin-1-ylmethyl-phenolato)(η5-cylopentadienyl)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

cyclopentadienyl titanium(IV) trichloride (1270-98-0) + 2,4-di-tert-butyl-6-(piperidin-1-ylmethyl)phenol (415688-70-9) → dichloro(2,4-di-tert-butyl-6-piperidin-1-ylmethyl-phenolato)(η5-cylopentadienyl)titanium (514791-78-7)

Guidance literature:

With n-butyl lithium; In tetrahydrofuran; hexane; byproducts: LiCl; under N2; n-BuLi in hexanes added dropwise to stirred soln. of ligand inTHF (-78°C); stirred (30 min); warmed to room temp. for 1 h; coo led to -78°C; Ti complex added; held at -78°C for 1 h; warmed to room temp.; stirred overnight; solvent removed under vac.; extd. with CH2Cl2; concd.; layered with light petroleum; cooled to 5°C; elem. anal.;

DOI:10.1016/S0022-328X(02)02106-X

upstream raw materials:

cyclopentadienyl titanium(IV) trichloride

2,4-di-tert-butyl-6-(piperidin-1-ylmethyl)phenol