(E)-1-trimethylsilyl-1-triphenylstannyl-1-hexene

Base Information

• Chemical Name: (E)-1-trimethylsilyl-1-triphenylstannyl-1-hexene
• CAS No.: 796055-87-3
• Molecular Formula: C₂₇H₃₄SiSn
• Molecular Weight: 505.362
• Mol file: 796055-87-3.mol

Synonyms:

Chemical Property of (E)-1-trimethylsilyl-1-triphenylstannyl-1-hexene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-1-trimethylsilyl-1-triphenylstannyl-1-hexene

There total 1 articles about (E)-1-trimethylsilyl-1-triphenylstannyl-1-hexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

1-(trimethylsilyl)-1-hexyne (3844-94-8) + isobutylmagnesium bromide (926-62-5) + triphenyltin chloride (639-58-7) → (E)-1-trimethylsilyl-1-triphenylstannyl-1-hexene (796055-87-3)

Guidance literature:

bis(cyclopentadienyl)titanium dichloride; In diethyl ether; byproducts: MgBrCl; under Ar; Cp2TiCl2 (5 mol%) added to soln. of i-BuMgBr in Et2O at 0°C; stirred at 0°C for 0.5 h; alkynylsilane added; stirred at 25°C for 6 h; evapd.; THF added; soln. of Ph3SnCl in THF added; stirred at 60°C for 8 h; quenched with satd. aq. NH4Cl; extd. with Et2O; org. layer washed with satd. aq. NH4Cl and H2O; dried over MgSO4; filtrate evapd. under vac.; column chromy. (silica gel, light petroleum ether); elem. anal.;

DOI:10.1016/j.jorganchem.2004.07.063

upstream raw materials:

1-(trimethylsilyl)-1-hexyne

isobutylmagnesium bromide

triphenyltin chloride