1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene

Base Information

Chemical Name:1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene
CAS No.:194232-33-2
Molecular Formula:C₄₈H₈₉IO₆Si₂
Molecular Weight:945.307
Hs Code.:

1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene

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Chemical Property of 1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene

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Technology Process of 1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene

There total 8 articles about 1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 194232-33-2
1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene

Guidance literature:: Multi-step reaction with 4 steps

1: TEA

2: H₂ / Ra/Ni / ethanol

3: tetrapropylammonium perruthenate, NMO / CH₂Cl₂; acetonitrile

With N-methyl-2-indolinone; tetrapropylammonium perruthennate; TEA; hydrogen; nickel; In ethanol; dichloromethane; acetonitrile;
DOI:10.1021/jo9708093

Reference yield:

: 153628-63-8
[(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

: 194232-33-2
1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) lithium hexamethyldisilazide, tetramethylethylenediamine / 1) THF, hexane, -78 deg C

2: LiAlH₄, LiI / diethyl ether / -78 °C

3: TEA

4: H₂ / Ra/Ni / ethanol

5: tetrapropylammonium perruthenate, NMO / CH₂Cl₂; acetonitrile

With lithium aluminium tetrahydride; N-methyl-2-indolinone; tetrapropylammonium perruthennate; N,N,N,N,-tetramethylethylenediamine; TEA; hydrogen; lithium iodide; lithium hexamethyldisilazane; nickel; In diethyl ether; ethanol; dichloromethane; acetonitrile;
DOI:10.1021/jo9708093

Reference yield:

: (4S,5R,6R)-7-(4-Methoxy-benzyloxy)-5-methoxymethoxy-4,6-dimethyl-heptan-3-one

: 194232-33-2
1-((8Z,13Z)-(2R,3R,4S,5S,6R,10R,11S,12R)-14-Iodo-3-methoxymethoxy-2,4,6,8,10,12-hexamethyl-5,11-bis-triisopropylsilanyloxy-tetradeca-8,13-dienyloxymethyl)-4-methoxy-benzene

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) lithium hexamethyldisilazide, tetramethylethylenediamine / 1) THF, hexane, -78 deg C

2: LiAlH₄, LiI / diethyl ether / -78 °C

3: TEA

4: H₂ / Ra/Ni / ethanol

5: tetrapropylammonium perruthenate, NMO / CH₂Cl₂; acetonitrile

With lithium aluminium tetrahydride; N-methyl-2-indolinone; tetrapropylammonium perruthennate; N,N,N,N,-tetramethylethylenediamine; TEA; hydrogen; lithium iodide; lithium hexamethyldisilazane; nickel; In diethyl ether; ethanol; dichloromethane; acetonitrile;
DOI:10.1021/jo9708093