[(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

Base Information

Chemical Name:[(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane
CAS No.:153628-63-8
Molecular Formula:C₂₆H₄₅IO₂Si
Molecular Weight:544.632
Hs Code.:

Synonyms:[(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

Suppliers and Price of [(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

There total 12 articles about [(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 153628-67-2
(Z)-(4R,5S,6R)-7-Benzyloxy-2,4,6-trimethyl-5-triisopropylsilanyloxy-hept-2-en-1-ol

: 153628-63-8
[(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

Guidance literature:: With methyltriphenoxyphosphonium iodide;
DOI:10.1016/S0040-4039(00)61480-6

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 153628-63-8
[(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / 2,6-lutidine

2: 96 percent / DIBAL-H / CH₂Cl₂

3: 92 percent / methyl triphenoxyphosphonium iodide

With 2,6-dimethylpyridine; methyltriphenoxyphosphonium iodide; diisobutylaluminium hydride; In dichloromethane;
DOI:10.1016/S0040-4039(00)61480-6

Reference yield:

: 79026-61-2
(R)-3-benzyloxy-2-methylpropanal

: 153628-63-8
[(Z)-(1S,2R)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-5-iodo-2,4-dimethyl-pent-3-enyloxy]-triisopropyl-silane

Guidance literature:: Multi-step reaction with 10 steps

1: 94 percent / Sn(OTf)2, N(Et)3

2: 99 percent / DIBAL-H / CH₂Cl₂

3: LiOH, H₂O₂

4: NEt₃

5: NEt₃

6: 62 percent / Dibal-H / CH₂Cl₂

7: 91 percent / pyridine

8: 100 percent / 2,6-lutidine

9: 96 percent / DIBAL-H / CH₂Cl₂

10: 92 percent / methyl triphenoxyphosphonium iodide

With pyridine; 2,6-dimethylpyridine; lithium hydroxide; tin(II) trifluoromethanesulfonate; methyltriphenoxyphosphonium iodide; dihydrogen peroxide; diisobutylaluminium hydride; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4039(00)61480-6