[(C₅H₅)(PPh₃)2RuCC(C₅H₃(Me)NCH=CHCO₂Me))]Br

Base Information

• Chemical Name: [(C₅H₅)(PPh₃)2RuCC(C₅H₃(Me)NCH=CHCO₂Me))]Br
• CAS No.: 1072161-71-7
• Molecular Formula: Br*C₅₄H₄₈NO₂P₂Ru
• Molecular Weight: 985.902
• Mol file: 1072161-71-7.mol

Synonyms:

Chemical Property of [(C₅H₅)(PPh₃)2RuCC(C₅H₃(Me)NCH=CHCO₂Me))]Br

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₅H₅)(PPh₃)2RuCC(C₅H₃(Me)NCH=CHCO₂Me))]Br

There total 1 articles about [(C₅H₅)(PPh₃)2RuCC(C₅H₃(Me)NCH=CHCO₂Me))]Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

methyl 4-bromocrotonate (1117-71-1) + [(C5H5)(PPh3)2RuCC(C5H3(Me)N))] (1072161-52-4) → [(C5H5)(PPh3)2RuCC(C5H3(Me)NCH=CHCO2Me))]Br (1072161-71-7)

Guidance literature:

In diethyl ether; (N2); std. Schlenk technique; bromide was added to soln. of Ru complex in Et2O; stirred overnight; filtered; washed; dried (vac.); elem. anal.;

DOI:10.1021/om800253e

Reference yield: 50.0%

potassium hexafluorophosphate (17084-13-8) + [(C5H5)(PPh3)2RuCC(C5H3(Me)NCH=CHCO2Me))]Br (1072161-71-7) → [(C5H5)(PPh3)2Ru=C=C(C5H3(Me)NCH2C(H)CH2CO2Me))](PF6)2

Guidance literature:

In chloroform; (N2); std. Schlenk technique; soln. of KPF6 and Ru complex in CHCl3 was stirred at ambient temp. for 3 d; volatiles removed; extd. (CH2Cl2); added to Et2O and cold THF; dried (vac.); elem. anal.;

DOI:10.1021/om800253e

upstream raw materials:

methyl 4-bromocrotonate

[(C₅H₅)(PPh₃)2RuCC(C₅H₃(Me)N))]