dichlorido(N,N-bis(2-pyridylmethyl)benzeneamine)copper(II)

Base Information

• Chemical Name: dichlorido(N,N-bis(2-pyridylmethyl)benzeneamine)copper(II)
• CAS No.: 498534-44-4
• Molecular Formula: C₁₈H₁₇Cl₂CuN₃
• Molecular Weight: 409.805
• Mol file: 498534-44-4.mol

Synonyms:

Chemical Property of dichlorido(N,N-bis(2-pyridylmethyl)benzeneamine)copper(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichlorido(N,N-bis(2-pyridylmethyl)benzeneamine)copper(II)

There total 2 articles about dichlorido(N,N-bis(2-pyridylmethyl)benzeneamine)copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.8%

N,N-bis(pyridin-2-ylmethyl)benzenamine (301668-92-8) + copper(II) chloride monohydrate → dichlorido(N,N-bis(2-pyridylmethyl)benzeneamine)copper(II) (498534-44-4)

Guidance literature:

In methanol; water; soln. of CuCl2*H2O in water was added dropwise to ligand in MeOH, some h; filtered, washed with acetone, dried in vacuo, recrystd. from MeCN; elem. anal.;

DOI:10.1016/S0020-1693(02)01063-0

Reference yield: 76.0%

N,N-bis(pyridin-2-ylmethyl)benzenamine (301668-92-8) + copper(II) choride dihydrate → dichlorido(N,N-bis(2-pyridylmethyl)benzeneamine)copper(II) (498534-44-4)

Guidance literature:

In methanol; CuCl2*2H2O in methanol added to organic ligand in methanol; after 3 days, the initial turquoise precipitate redissolved and grass-green rods of product deposited;

DOI:10.1016/j.poly.2006.12.005

Reference yield: 95.2%

ammonium hexafluorophosphate + dichlorido(N,N-bis(2-pyridylmethyl)benzeneamine)copper(II) (498534-44-4) + water (7732-18-5) → [CuCl(N,N-bis(2-pyridylmethyl)aniline)]PF6*H2O

Guidance literature:

In acetonitrile; byproducts: NH4Cl; NH4PF6 was added to suspn. of Cu-complex in MeCN, refluxed for 1 h understirring; filtered, evapd. to dryness, washed with water, recrystd. from acetone; elem. anal.;

DOI:10.1016/S0020-1693(02)01063-0

upstream raw materials:

N,N-bis(pyridin-2-ylmethyl)benzenamine