[Li(tetrahydrofuran)2(N,N,N',N'-tetramethylethylenediamine)][Ph₃Al(tetramethylpiperidine)]

Base Information

• Chemical Name: [Li(tetrahydrofuran)2(N,N,N',N'-tetramethylethylenediamine)][Ph₃Al(tetramethylpiperidine)]
• CAS No.: 1246267-37-7
• Molecular Formula: C₁₄H₃₂LiN₂O₂*C₂₇H₃₃AlN
• Molecular Weight: 665.909
• Mol file: 1246267-37-7.mol

Synonyms:

Chemical Property of [Li(tetrahydrofuran)2(N,N,N',N'-tetramethylethylenediamine)][Ph₃Al(tetramethylpiperidine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Li(tetrahydrofuran)2(N,N,N',N'-tetramethylethylenediamine)][Ph₃Al(tetramethylpiperidine)]

There total 1 articles about [Li(tetrahydrofuran)2(N,N,N',N'-tetramethylethylenediamine)][Ph₃Al(tetramethylpiperidine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + triphenylaluminum etherate (856321-14-7) + N,N,N,N,-tetramethylethylenediamine (110-18-9) + 2,2,6,6-tetramethylpiperidinyl-lithium (38227-87-1) → [Li(tetrahydrofuran)2(N,N,N',N'-tetramethylethylenediamine)][Ph3Al(tetramethylpiperidine)] (1246267-37-7)

Guidance literature:

In tetrahydrofuran; toluene; under Ar; soln. of Li compd. in toluene dropped into soln. of Et2OAlPh3 in THF at -78°C, mixt. stirred at room temp. for 2 h, solid sepd.and dissolved in THF/tetramethylethylenediamine; soln. concd., soln. filtered, filtrate stored at -20°C, crystals isolated and gently dried under vac.; elem. anal.;

DOI:10.1039/c0nj00136h

upstream raw materials:

tetrahydrofuran

triphenylaluminum etherate

N,N,N,N,-tetramethylethylenediamine

2,2,6,6-tetramethylpiperidinyl-lithium