(μ-p-MeC6H4Se)2Fe2(CO)6

Base Information

Chemical Name:(μ-p-MeC6H4Se)2Fe2(CO)6
CAS No.:172367-46-3
Molecular Formula:C₂₀H₁₄Fe₂O₆Se₂
Molecular Weight:619.942
Hs Code.:

Synonyms:

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Chemical Property of (μ-p-MeC6H4Se)2Fe2(CO)6

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Technology Process of (μ-p-MeC6H4Se)2Fe2(CO)6

There total 21 articles about (μ-p-MeC6H4Se)2Fe2(CO)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 7782-49-2
selenium

: 17685-52-8
triiron dodecarbonyl

: [(η(5)-C5H5)(CO)2Re*CC6H5]BBr4

: 4294-57-9
para-methylphenylmagnesium bromide

: tricarbonylcyclopentadienylrhenium

: 172367-46-3,350039-26-8
(μ-p-MeC6H4Se)2Fe2(CO)6

: 349606-53-7
C₅H₅Re(CO)2Fe(CO)3CC₆H₅SeC₆H₄CH₃

Guidance literature:: In tetrahydrofuran; (N2); stirring a mixt. of selenium and magnesium compd. in THF at room temp. for 20 min, addn. of iron carbonyl, stirring at room temp. for 30 min, cooling to -100°C, poured to rhenium complex, warming to -80°C, stirring for 6 h; evapn. at -50 to -40°C, column chromy (Al2O3, petroleum ether, petroleum ether/CH2Cl2 20:1, petroleum ether/CH2Cl2/Et2O 10:1:1), evapn., recrystn. (petroleum ether/CH2Cl2, -80°C); elem. anal.;
DOI:10.1021/om001035a

Reference yield: 56.0%

: 17685-52-8
triiron dodecarbonyl

: 37773-23-2
p-Selenocresol

: 622-78-6
Benzyl isothiocyanate

: 172367-46-3,350039-26-8
(μ-p-MeC6H4Se)2Fe2(CO)6

: (μ-p-MeC6H4Se)(μ-PhCH2N(H)C=S)Fe2(CO)6

Guidance literature:: With Et₃N; In tetrahydrofuran; under N2 atm. Fe3(CO)12, p-MeC6H4SeH, and Et3N in THF were stirred for 0.5 h at room temp., PhCH2NCS was stirred for 16 h; solvent was removed under reduced pressure, chromy. (TLC, CH2Cl2-petroleum ether 1:5); elem. anal.;
DOI:10.1016/S0022-328X(01)00766-5

Reference yield: 41.0%

: 17685-52-8
triiron dodecarbonyl

: 37773-23-2
p-Selenocresol

: 103-72-0
phenyl isothiocyanate

: 172367-46-3,350039-26-8
(μ-p-MeC6H4Se)2Fe2(CO)6

: 353760-14-2
(μ-p-MeC6H4Se)(μ-PhN(H)C=S)Fe2(CO)6

Guidance literature:: With Et₃N; In tetrahydrofuran; under N2 atm. Fe3(CO)12, p-MeC6H4SeH, and Et3N in THF were stirred for 0.5 h at room temp., PhNCS was stirred for 16 h; solvent was removed under reduced pressure, chromy. (TLC, CH2Cl2-petroleum ether 1:3); elem. anal.;
DOI:10.1016/S0022-328X(01)00766-5