2-(4'-methoxyphenyl)ethyl-3,4-dimethylphosphacymantrene

Base Information

• Chemical Name: 2-(4'-methoxyphenyl)ethyl-3,4-dimethylphosphacymantrene
• CAS No.: 507233-72-9
• Molecular Formula: C₁₈H₁₈MnO₄P
• Molecular Weight: 384.25
• Mol file: 507233-72-9.mol

Synonyms:

Chemical Property of 2-(4'-methoxyphenyl)ethyl-3,4-dimethylphosphacymantrene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(4'-methoxyphenyl)ethyl-3,4-dimethylphosphacymantrene

There total 1 articles about 2-(4'-methoxyphenyl)ethyl-3,4-dimethylphosphacymantrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

2-(1'-hydroxyethyl)-3,4-dimethylphosphacymantrene (69593-19-7) + methoxybenzene (100-66-3) → 2-(4'-methoxyphenyl)ethyl-3,4-dimethylphosphacymantrene (506445-06-3,507233-72-9)

Guidance literature:

With AlCl₃; In dichloromethane; (N2); placing of anisole and Mn(CO)3(HOCH(Me)C4H2PMe2) in Schlenk tube; addn. of CH2Cl2 via septum, cooling to 0°C, addn. of AlCl3; monitoring by NMR for 2 h; dilution with CH2Cl2, addn. of satd. aq. soln. of NaHCO3; washing with brine, collection of organic layer; drying with MgSO4; removal under vac., chromy. over silica gel with 90:10 hexane/ether mixt. as eluent; as mixt. of two diastereomers;

DOI:10.1021/om020981j

upstream raw materials:

2-(1'-hydroxyethyl)-3,4-dimethylphosphacymantrene

methoxybenzene