(bipyridine)(terpyridine)(4-iodophenylcyanamide)ruthenium(II) hexafluorophosphate

Base Information

• Chemical Name: (bipyridine)(terpyridine)(4-iodophenylcyanamide)ruthenium(II) hexafluorophosphate
• CAS No.: 352020-07-6
• Molecular Formula: C₃₂H₂₃IN₇Ru*F₆P
• Molecular Weight: 878.52
• Mol file: 352020-07-6.mol

Synonyms:

Chemical Property of (bipyridine)(terpyridine)(4-iodophenylcyanamide)ruthenium(II) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (bipyridine)(terpyridine)(4-iodophenylcyanamide)ruthenium(II) hexafluorophosphate

There total 1 articles about (bipyridine)(terpyridine)(4-iodophenylcyanamide)ruthenium(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

ammonium hexafluorophosphate + silver(I) hexafluorophosphate (26042-63-7) + 2,2'-bipyridine(2,2':6',2''-terpyridine)chlororuthenium(II) hexafluorophosphate (83572-47-8) + N-(4-iodophenyl)cyanamide (352020-08-7) → (bipyridine)(terpyridine)(4-iodophenylcyanamide)ruthenium(II) hexafluorophosphate (352020-07-6)

Guidance literature:

In acetone; byproducts: AgCl; mixt. of the Ru complex and AgPF6 refluxed with stirring for 4 h under Ar, a tenfold excess of ligand was added, soln. was stirred and refluxed for 4 h under Ar, then at room temp. overnight; AgCl was filtered off, solid NH4PF6 was added to the filtrate, soln. wasconcd., Et2O was added, ppt. was filtered, washed with Et2O, dried unde r vac., chromd., recrystd. from toluene and MeCN; elem. anal.;

DOI:10.1016/S0020-1693(01)00382-6

upstream raw materials:

silver(I) hexafluorophosphate

2,2'-bipyridine(2,2':6',2''-terpyridine)chlororuthenium(II) hexafluorophosphate

N-(4-iodophenyl)cyanamide