3-(p-iodobenzoyl)-1,1'-biferrocenylene

Base Information

Chemical Name:3-(p-iodobenzoyl)-1,1'-biferrocenylene
CAS No.:1358749-02-6
Molecular Formula:C₂₇H₁₉Fe₂IO
Molecular Weight:598.046
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-(p-iodobenzoyl)-1,1'-biferrocenylene

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Technology Process of 3-(p-iodobenzoyl)-1,1'-biferrocenylene

There total 1 articles about 3-(p-iodobenzoyl)-1,1'-biferrocenylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

: 11105-90-1
bis(μ-fulvalenediyl)diiron

: 1711-02-0
4-iodobenzoic acid chloride

: 1358749-02-6
3-(p-iodobenzoyl)-1,1'-biferrocenylene

: 1358748-93-2
2-(p-iodobenzoyl)-1,1'-biferrocenylene

Guidance literature:: With AlCl₃; In carbon disulfide; 1,2-dichloro-ethane; under N2; Fe complex in dry CS2 heated to 50°C; soln. of IC6H4COCl and AlCl3 (2.3 equiv.) in dry 1,2-dichloroethane added rapidly; after 3-12 h additional portion of solid AlCl3 (2.3 equiv.) added; reacted for12 h; cooled to room temp.; H2O added; aq. layer acidified to pH 1 (HCl); extd. (CH2Cl2); combined org. layers washed (satd. NaHCO3, water); dried (Na2SO4); solvent evapd. under reduced pressure; sepd. by flash column chromy. (silica, CH2Cl2-n-hexane 80:20, CH2Cl2); elem. anal.;
DOI:10.1021/om201215w

Reference yield: 75.0%

: 1358749-02-6
3-(p-iodobenzoyl)-1,1'-biferrocenylene

: borane tert-butylamine

: 1358749-07-1
3-(p-iodobenzyl)-1,1'-biferrocenylene

Guidance literature:: With AlCl₃; In dichloromethane; t-BuNH2*BH3 added at 0°C to suspn. of AlCl3 in CH2Cl2; stirred for 15 min; soln. of Fe complex in CH2Cl2 added dropwise; stirred at room temp. for 1 h; quenched carefully with aq. HCl; aq. layer extd. (CH2Cl2); combined org.layers washed with brine; dried (Na2SO4); solvent evapd. under reduced pressure; purified by flash column chromy. (silica, CH2Cl2-n-hexane 80:2 0); elem. anal.;
DOI:10.1021/om201215w