(+/-)-[(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl-1-diphenylphosphinyl-methylethane)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

Base Information

Chemical Name:(+/-)-[(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl-1-diphenylphosphinyl-methylethane)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate
CAS No.:192825-00-6
Molecular Formula:C₅₃H₅₇P₃Rh*F₆P
Molecular Weight:1034.83
Hs Code.:

(+/-)-[(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl-1-diphenylphosphinyl-methylethane)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

Synonyms:

Suppliers and Price of (+/-)-[(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl-1-diphenylphosphinyl-methylethane)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (+/-)-[(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl-1-diphenylphosphinyl-methylethane)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (+/-)-[(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl-1-diphenylphosphinyl-methylethane)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

There total 1 articles about (+/-)-[(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl-1-diphenylphosphinyl-methylethane)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 17084-13-8
potassium hexafluorophosphate

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 154368-08-8
(+/-)-(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl)-1-diphenylphosphinyl-methylethane

: 192825-00-6,192824-97-8
(+/-)-[(1-dibenzophospholylmethyl-1-di(3,5-dimethylphenyl)phosphinylmethyl-1-diphenylphosphinyl-methylethane)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

Guidance literature:: In dichloromethane; acetone; byproducts: KCl; N2-atmosphere; stirring Rh-complex (in CH2Cl2) with 2 equiv. KPF6 (in Me2CO) for 5 min, addn. of 2 equiv. of ligand (in CH2Cl2), stirring for 20min; evapn. (vac.), dissoln. in CH2Cl2, drying (Na2SO4), centrifugation off of KCl, concn., pptn. on Et2O addn.; elem. anal.;
DOI:10.1016/S0022-328X(96)06930-6