Ir(tht)2(PPh₃)Cl₃]

Base Information

Chemical Name:Ir(tht)2(PPh₃)Cl₃]
CAS No.:1375970-01-6
Molecular Formula:C₂₆H₃₁Cl₃IrPS₂
Molecular Weight:737.217
Hs Code.:

Ir(tht)2(PPh<sub>3</sub>)Cl<sub>3</sub>]

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Chemical Property of Ir(tht)2(PPh₃)Cl₃]

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Technology Process of Ir(tht)2(PPh₃)Cl₃]

There total 1 articles about Ir(tht)2(PPh₃)Cl₃] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 35925-64-5,445022-31-1
[Ir(tetrahydrothiophene)₃Cl₃]

: 603-35-0
triphenylphosphine

: 1375970-01-6
Ir(tht)2(PPh₃)Cl₃]

Guidance literature:: In decalin; (Ar) mixt. Ir complex and PPh3 (1:1) in decalin was heated to reflux for2 h; react. mixt. was cooled to room temp., solvent was removed in vacuo, residue was dissolved in CH2Cl2 and filtered through Celite, filtrate was evapd., crystn. from CH2Cl2-hexane at room temp.; elem. anal.;
DOI:10.1021/om300325y

Reference yield: 75.0%

: 1375970-01-6
Ir(tht)2(PPh₃)Cl₃]

: 7650-91-1
benzyldiphenylphosphane

: [Ir(benzyldiphenylphosphine)(benzyldiphenylphosphine^(1-))(tetrahydrothiophene)Cl₂]

Guidance literature:: In decalin; (Ar) mixt. Ir complex and ligand in decalin was heated to reflux for 1 h; react. mixt. was cooled to room temp., solvent was removed in vacuo, residue was filtered through Celite, filtrate was concd., crystn. from CH2Cl2-hexane at room temp.; elem. anal.;
DOI:10.1021/om300325y

Reference yield: 35.0%

: 1375970-01-6
Ir(tht)2(PPh₃)Cl₃]

: 3974-71-8
3-trifluoromethyl-5-(2-pyridyl)pyrazole

: 7650-91-1
benzyldiphenylphosphane

: [Ir(benzyldiphenylphosphine^(1-))(5-pyridyl-3-trifluoromethyl-1H-pyrazole^(1-))2]

Guidance literature:: With Na₂CO₃; In decalin; (Ar) mixt. Ir complex and bdpH in decalin was heated at 180°C for4.5 h, react. mixt. was cooled to room temp., fppzH and Na2CO3 were add ed, heated to reflux for 16 h; react. mixt. was cooled, solvent was evapd., chromy. on silica (EtOAc-hexane 1:1), crystn. from CH2Cl2 and hexane at room temp.;
DOI:10.1021/om300325y