Fe(CO)3(C₆H₅CHCHC(CO)CHCHC₆H₅)

Base Information

Chemical Name:Fe(CO)3(C₆H₅CHCHC(CO)CHCHC₆H₅)
CAS No.:167556-86-7
Molecular Formula:C₂₁H₁₄FeO₄
Molecular Weight:386.187
Hs Code.:

Fe(CO)3(C<sub>6</sub>H<sub>5</sub>CHCHC(CO)CHCHC<sub>6</sub>H<sub>5</sub>)

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Chemical Property of Fe(CO)3(C₆H₅CHCHC(CO)CHCHC₆H₅)

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Technology Process of Fe(CO)3(C₆H₅CHCHC(CO)CHCHC₆H₅)

There total 4 articles about Fe(CO)3(C₆H₅CHCHC(CO)CHCHC₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

: 138783-45-6,168558-94-9
Fe(CO)3(C₆H₅CHCHC(O)CHCHC₆H₅)

: 917-54-4
methyllithium

: 167556-86-7
Fe(CO)3(C₆H₅CHCHC(CO)CHCHC₆H₅)

: Fe₂(CO)6(C₆H₅CHCH)2

Guidance literature:: With CuI; In diethyl ether; byproducts: dibenzylideneacetone; N2-atmosphere; addn. of 2 equiv. MeLi to CuI at -78°C, stirring for 15 min, warming to -23°C over 45 min, cooling to -78°C,addn. of 0.5 equiv. of Fe-complex, stirring (-78°C, 3.5 h); quenching with aq. NH4Cl/NH4OH at -20°C, warming to room temp., extn. into Et2O, drying (Na2SO4), solvent removal (reduced pressure), chromy. (SiO2, hexane/EtOAc);
DOI:10.1016/S0277-5387(97)00052-1

Reference yield: 9.0%

: 154965-27-2
Fe2(CO)8[μ-η(2),η(2)-C(O)(CH=CHPh)2]

: 201230-82-2
carbon monoxide

: 167556-86-7
Fe(CO)3(η(4)-OhCH=CH=C(CH=CHPh)=C=O)

: 168558-95-0
Fe2(CO)6[μ-η(3),η(3)-C(CH=CHPh)2]

Guidance literature:: With MeLi; In tetrahydrofuran; diethyl ether; addn. of MeLi (in Et2O) to Fe-complex (in THF) under 1.1 atm CO at -78°C, standing at -78°C for 1 h, warming to room temp. over 3 h; evapn. (vac.), chromy. (SiO2, hexane/AcOEt=98:2); elem. anal.;
DOI:10.1016/0022-328X(95)05457-Z

Reference yield: 7.0%

: Fe(CO)4[η(2)(CO)(CH=CHPh)2]

: 201230-82-2
carbon monoxide

: 167556-86-7
Fe(CO)3(η(4)-OhCH=CH=C(CH=CHPh)=C=O)

: 168558-95-0
Fe2(CO)6[μ-η(3),η(3)-C(CH=CHPh)2]

Guidance literature:: With MeLi; In tetrahydrofuran; diethyl ether; CO-atmosphere; addn. of MeLi (in Et2O) to Fe-complex (in THF) at -78°C, standing at -78°C for 1 h, warming to room temp. over 3 h; evapn. (vac.), chromy. (SiO2);
DOI:10.1016/0022-328X(95)05457-Z